Advances in the use of CO 2 as a renewable feedstock for the synthesis of polymers

B Grignard, S Gennen, C Jérôme, AW Kleij… - Chemical Society …, 2019 - pubs.rsc.org
Carbon dioxide offers an accessible, cheap and renewable carbon feedstock for synthesis.
Current interest in the area of carbon dioxide valorisation aims at new, emerging …

A quest for polycarbonates provided via sustainable epoxide/CO 2 copolymerization processes

SJ Poland, DJ Darensbourg - Green Chemistry, 2017 - pubs.rsc.org
The present review highlights advances in the copolymerization of carbon dioxide (CO2)
and epoxides (oxiranes) to produce polycarbonates. Specifically, focus has been given to …

Switchable Catalysis Improves the Properties of CO2-Derived Polymers: Poly(cyclohexene carbonate-b-ε-decalactone-b-cyclohexene carbonate) Adhesives …

GS Sulley, GL Gregory, TTD Chen… - Journal of the …, 2020 - ACS Publications
Carbon dioxide/epoxide copolymerization is an efficient way to add value to waste CO2 and
to reduce pollution in polymer manufacturing. Using this process to make low molar mass …

Ring-opening copolymerization (ROCOP): synthesis and properties of polyesters and polycarbonates

S Paul, Y Zhu, C Romain, R Brooks, PK Saini… - Chemical …, 2015 - pubs.rsc.org
Controlled routes to prepare polyesters and polycarbonates are of interest due to the
widespread application of these materials and the opportunities provided to prepare new …

Carbon dioxide-based functional polycarbonates: Metal catalyzed copolymerization of CO2 and epoxides

Y Wang, DJ Darensbourg - Coordination Chemistry Reviews, 2018 - Elsevier
Proof of principles studies by Inoue and coworkers in the late 1960s clearly illustrated the
poorly controlled coupling of CO 2 and epoxides to provide polycarbonates. These early …

Synthesis and properties of CO2-based plastics: Environmentally-friendly, energy-saving and biomedical polymeric materials

Y Xu, L Lin, M Xiao, S Wang, AT Smith, L Sun… - Progress in Polymer …, 2018 - Elsevier
Production of biodegradable plastics from carbon dioxide, particularly as a means of
recycling industrial waste gas, is a promising advancement in environmental and energy …

Update and challenges in carbon dioxide‐based polycarbonate synthesis

J Huang, JC Worch, AP Dove, O Coulembier - ChemSusChem, 2020 - Wiley Online Library
The utilization of carbon dioxide as a comonomer to produce polycarbonates has attracted a
great deal of attention from both industrial and academic communities because it promises …

Catalysts for CO2/epoxide ring-opening copolymerization

G Trott, PK Saini, CK Williams - … Transactions of the …, 2016 - royalsocietypublishing.org
This article summarizes and reviews recent progress in the development of catalysts for the
ring-opening copolymerization of carbon dioxide and epoxides. The copolymerization is an …

Chemoselective polymerizations from mixtures of epoxide, lactone, anhydride, and carbon dioxide

C Romain, Y Zhu, P Dingwall, S Paul… - Journal of the …, 2016 - ACS Publications
Controlling polymer composition starting from mixtures of monomers is an important, but
rarely achieved, target. Here a single switchable catalyst for both ring-opening …

Functional polycarbonates from carbon dioxide and tailored epoxide monomers: degradable materials and their application potential

M Scharfenberg, J Hilf, H Frey - Advanced Functional Materials, 2018 - Wiley Online Library
Aliphatic polycarbonates synthesized from carbon dioxide (CO2) and epoxides are resource‐
saving, highly biocompatible and biodegradable polymers. Since the discovery of the …