Electrochemical late-stage functionalization

Y Wang, S Dana, H Long, Y Xu, Y Li… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …

Methodologies and strategies for selective borylation of C–Het and C–C bonds

M Wang, Z Shi - Chemical Reviews, 2020 - ACS Publications
Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …

Single Electron Transfer-Induced Redox Processes Involving N-(Acyloxy)phthalimides

SK Parida, T Mandal, S Das, SK Hota, S De Sarkar… - ACS …, 2021 - ACS Publications
The past decade has witnessed the emergence of N-(acyloxy) phthalimides (NHPI esters)
and its derivatives at the forefront of synthetic methods facilitating the construction of diverse …

Acyclic twisted amides

G Meng, J Zhang, M Szostak - Chemical reviews, 2021 - ACS Publications
In this contribution, we provide a comprehensive overview of acyclic twisted amides,
covering the literature since 1993 (the year of the first recognized report on acyclic twisted …

Iridium-catalyzed asymmetric allylic substitution reactions

Q Cheng, HF Tu, C Zheng, JP Qu, G Helmchen… - Chemical …, 2018 - ACS Publications
In this review, we summarize the origin and advancements of iridium-catalyzed asymmetric
allylic substitution reactions during the past two decades. Since the first report in 1997, Ir …

Electrochemical Ring-Opening Dicarboxylation of Strained Carbon–Carbon Single Bonds with CO2: Facile Synthesis of Diacids and Derivatization into Polyesters

LL Liao, ZH Wang, KG Cao, GQ Sun… - Journal of the …, 2022 - ACS Publications
Diacids are important monomers in the polymer industry to construct valuable materials.
Dicarboxylation of unsaturated bonds, such as alkenes and alkynes, with CO2 has been …

Electroreductive Dicarboxylation of Unactivated Skipped Dienes with CO2

W Zhang, LL Liao, L Li, Y Liu, LF Dai… - Angewandte Chemie …, 2023 - Wiley Online Library
Carboxylation of easily available alkenes with CO2 is highly important to afford value‐added
carboxylic acids. Although dicarboxylation of activated alkenes, especially 1, 3‐dienes, has …

Hexagonal mesoporous silica supported ultrasmall copper oxides for oxidative amidation of carboxylic acids

RG Kadam, M Petr, R Zbořil… - ACS Sustainable …, 2018 - ACS Publications
Hexagonal mesoporous silica (HMS) supported copper oxide nanoparticles were prepared
by a one-pot sol–gel synthesis, and their physicochemical properties were determined by …

Cross-coupling and related reactions: connecting past success to the development of new reactions for the future

LC Campeau, N Hazari - Organometallics, 2018 - ACS Publications
Cross-coupling reactions, which were discovered almost 50 years ago, are widely used in
both industry and academia. Even though cross-coupling reactions now represent mature …

Arylcarboxylation of unactivated alkenes with CO2 via visible-light photoredox catalysis

W Zhang, Z Chen, YX Jiang, LL Liao, W Wang… - Nature …, 2023 - nature.com
Photocatalytic carboxylation of alkenes with CO2 is a promising and sustainable strategy to
synthesize high value-added carboxylic acids. However, it is challenging and rarely …