Amavadin, a vanadium natural complex: Its role and applications

JAL da Silva, JJRF da Silva, AJL Pombeiro - Coordination Chemistry …, 2013 - Elsevier
Amavadin (also spelled amavadine) is an intriguing vanadium (IV) complex that occurs, at
least, in the fungus Amanita muscaria (L.: Fr.) Hook. Its biological role has not yet been …

Trigonal bipyramidal or square pyramidal coordination geometry? Investigating the most potent geometry for vanadium phosphatase inhibitors

DC Crans, ML Tarlton… - European Journal of …, 2014 - Wiley Online Library
The five‐coordinate geometry is an important factor in phosphoryl group transfer, particularly
for phosphate ester hydrolysis. In the following review we analyze the five‐coordinate …

[图书][B] Thermochromic and thermotropic materials

A Seeboth, D Lötzsch - 2013 - books.google.com
Chromogenic materials change their optical properties in response to an external stimulus.
Due to their potential applications as light valve (eg, in sun protecting glazing) or as …

Interdependence of Structure, Morphology, and Phase Transitions in CVD Grown VO2 and V2O3 Nanostructures

D Graf, J Schläfer, S Garbe, A Klein… - Chemistry of …, 2017 - ACS Publications
Phase selective chemical vapor deposition of nanostructured vanadium dioxide (VO2) and
sesquioxide (V2O3) was achieved by deploying [V (OR) 4] n (R= t Bu, n= 1 (1), R= Et, n= 3 …

Nonoxido vanadium (IV) compounds involving dithiocarbazate-based tridentate ONS ligands: synthesis, electronic and molecular structure, spectroscopic and redox …

S Kundu, D Mondal, K Bhattacharya, A Endo… - Inorganic …, 2015 - ACS Publications
A new series of nonoxido vanadium (IV) compounds [VL2](L= L1–L3)(1–3) have been
synthesized using dithiocarbazate-based tridentate Schiff-base ligands H2L1–H2L3 …

Nonoxidovanadium(IV) Complex-Catalyzed Synthesis of 2-Amino-3-cyano-4H-pyrans/4H-chromenes, Biscoumarins, and Xanthenes under Green Conditions

MR Maurya, SK Maurya, N Kumar… - The Journal of Organic …, 2024 - ACS Publications
Reaction of [VIVO (acac) 2](Hacac= acetylacetone) with a Mannich base, N, N, N′, N′-
tetrakis (2-hydroxy-3, 5-di-tert-butyl benzyl)-1, 2-diaminoethane (H4L, I) in a 1: 1 molar ratio …

Octakis(tert-butoxo)dicerium(IV) [Ce2(OtBu)8]: Synthesis, Characterization, Decomposition, and Reactivity

J Schläfer, W Tyrra, S Mathur - Inorganic Chemistry, 2014 - ACS Publications
An advanced synthesis for the homometallic derivative [Ce2 (O t Bu) 8](1) starting from [Ce
(O t Bu) 2 {N (SiMe3) 2} 2] was developed. Structural characterization of a cerium (IV) …

A rare example of four-coordinate nonoxido vanadium (IV) alkoxide in the solid state: structure, spectroscopy, and magnetization dynamics

D Stinghen, M Atzori, CM Fernandes… - Inorganic …, 2018 - ACS Publications
The distorted tetrahedral [V (OAd) 4] alkoxide (OAd= 1-adamantoxide, complex 1) is the first
homoleptic, mononuclear vanadium (IV) alkoxide to be characterized in the solid state by X …

Simultaneous formation of non-oxidovanadium (iv) and oxidovanadium (v) complexes incorporating phenol-based hydrazone ligands in aerobic conditions

N Biswas, S Bera, N Sepay, A Pal, T Halder… - New Journal of …, 2020 - pubs.rsc.org
A new family of non-oxidovanadium (IV)[VIV (L) 2](1–4) complexes along with methoxy
bonded oxidovanadium (V)[VVO (L)(OCH3)](5 and 6) and [VVO (L)(OCH3)] 2 (7 and 8) …

Catalytic Activity of a Titanium(IV)/Iron(II) Heterometallic Alkoxide in the Ring‑Opening Polymerization of ε-Caprolactone and rac-Lactide

SOK Giese, C Egevardt, AL Rüdiger, EL Sá… - Journal of the Brazilian …, 2015 - SciELO Brasil
The activity of the heterometallic alkoxide [FeCl {Ti2 (OiPr) 9}](1) towards polymerization of
rac-lactide (rac-LA) and ε-caprolactone (ε-CL) was investigated in toluene solution and in …