Direct enzymatic bioelectrocatalysis: differentiating between myth and reality

RD Milton, SD Minteer - Journal of the Royal Society …, 2017 - royalsocietypublishing.org
Enzymatic bioelectrocatalysis is being increasingly exploited to better understand
oxidoreductase enzymes, to develop minimalistic yet specific biosensor platforms, and to …

Methodologies for “wiring” redox proteins/enzymes to electrode surfaces

NDJ Yates, MA Fascione… - Chemistry–A European …, 2018 - Wiley Online Library
The immobilization of redox proteins or enzymes onto conductive surfaces has application in
the analysis of biological processes, the fabrication of biosensors, and in the development of …

An intelligent portable biosensor for fast and accurate nitrate determination using cyclic voltammetry

J Massah, KA Vakilian - Biosystems Engineering, 2019 - Elsevier
Highlights•The system had a decision making unit implemented in a smartphone
application.•The device was usable up to at least 10 days after the enzyme …

Bioinorganic systems responsive to the diatomic gases O2, NO, and CO: From biological sensors to therapy

LG de Franca Lopes, FSG Júnior, AKM Holanda… - Coordination Chemistry …, 2021 - Elsevier
The diatomic molecules, O 2, NO and CO, have had a myriad of roles in biology. Due to this,
nature has developed many sensing proteins to perceive and respond to changes in the …

Enzymatic bioelectrosynthetic ammonia production: recent electrochemistry of nitrogenase, nitrate reductase, and nitrite reductase

RD Milton, SD Minteer - ChemPlusChem, 2017 - Wiley Online Library
As an essential component of amino acids and nucleic acids, nitrogen (N) is a key element
of life. For atmospheric (dinitrogen, N2) and environmental (nitrate and nitrite, NO3− and …

A portable nitrate biosensing device using electrochemistry and spectroscopy

KA Vakilian, J Massah - IEEE Sensors Journal, 2018 - ieeexplore.ieee.org
So far, several enzyme-based electrochemical biosensors have been developed for nitrate
concentration determination. Generally, nitrate measurement in these methods is based on …

A fuzzy-based decision making software for enzymatic electrochemical nitrate biosensors

KA Vakilian, J Massah - Chemometrics and Intelligent Laboratory Systems, 2018 - Elsevier
So far, many analytical biosensors have been introduced to determine the concentration of a
wide variety of analytes in environmental and agricultural samples. However, a major part of …

[HTML][HTML] Electrochemically driven catalysis of the bacterial molybdenum enzyme YiiM

P Kalimuthu, JR Harmer, M Baldauf, AH Hassan… - … et Biophysica Acta (BBA …, 2022 - Elsevier
Abstract The Mo-dependent enzyme YiiM enzyme from Escherichia coli is a member of the
sulfite oxidase family and shares many similarities with the well-studied human …

A highly sensitive and stable electrochemical nitrate biosensor

P Kalimuthu, T Kruse, PV Bernhardt - Electrochimica Acta, 2021 - Elsevier
We report an electrochemical nitrate biosensor incorporating the enzyme nitrate reductase
(NR) from the fungus Neurospora crassa entrapped within a polymeric chitosan matrix on a …

A nitrate enzymatic biosensor based on optimized machine learning techniques

KA Vakilian - 2022 9th Iranian Joint Congress on Fuzzy and …, 2022 - ieeexplore.ieee.org
Many enzymatic biosensing devices have been developed for specific and selective nitrate
detection over the last two decades. They generally use the nitrate-nitrite redox reaction to …