The electronic applications of stable diradicaloids: present and future

X Hu, W Wang, D Wang, Y Zheng - Journal of Materials Chemistry C, 2018 - pubs.rsc.org
Organic molecules with unpaired electrons are intriguing for advanced applications in
molecular electronics, spintronics and organic batteries, as well as other possible …

MoS2 Quantum Dot Growth Induced by S Vacancies in a ZnIn2S4 Monolayer: Atomic-Level Heterostructure for Photocatalytic Hydrogen Production

S Zhang, X Liu, C Liu, S Luo, L Wang, T Cai, Y Zeng… - ACS …, 2018 - ACS Publications
It is highly demanded to steer the charge flow in photocatalysts for efficient photocatalytic
hydrogen reactions (PHRs). In this study, we developed a smart strategy to position MoS2 …

Dearomatization Approach Toward a Superbenzoquinone‐Based Diradicaloid, Tetraradicaloid, and Hexaradicaloid

G Li, Y Han, Y Zou, JJC Lee, Y Ni, J Wu - Angewandte Chemie, 2019 - Wiley Online Library
Reported here is the step‐by‐step dearomatization of a highly aromatic polycyclic aromatic
hydrocarbon (PAH), the hexa‐peri‐hexabenzocoronene (also called as “superbenzene”), to …

[HTML][HTML] Design of an open-shell nitrogen-centered diradicaloid with tunable stimuli-responsive electronic properties

B Huang, H Kang, CW Zhang, XL Zhao, X Shi… - Communications …, 2022 - nature.com
Organic diradicaloids usually display an open-shell singlet ground state with significant
singlet diradical character (y 0) which endow them with intriguing physiochemical properties …

Quinoidal Azaacenes: 99% Diradical Character

SN Intorp, M Hodecker, M Müller… - Angewandte …, 2020 - Wiley Online Library
Quinoidal azaacenes with almost pure diradical character (y= 0.95 to y= 0.99) were
synthesized. All compounds exhibit paramagnetic behavior investigated by EPR and NMR …

Nitrogen analogues of Chichibabin's and Müller's hydrocarbons with small singlet–triplet energy gaps

X Hu, H Chen, L Zhao, M Miao, J Han… - Chemical …, 2019 - pubs.rsc.org
Nitrogen analogues of Chichibabin's and Müller's hydrocarbons, DPh-D and TPh-D, based
on 1, 2, 4-benzotriazinyl (Blatter) were studied. The two diradicaloids with good chemical …

Air stable high-spin blatter diradicals: non-Kekulé versus Kekulé structures

X Hu, L Zhao, H Chen, Y Ding, YZ Zheng… - Journal of Materials …, 2019 - pubs.rsc.org
Air stable high-spin diradicals under ambient conditions are relatively rare. We report two 1,
2, 4-benzotriazinyl based diradicals, non-Kekulé o-DBT and Kekulé p-DBT, with a highly …

[HTML][HTML] A BODIPY-bridged bisphenoxyl diradicaloid: Solvent-dependent diradical character and physical properties

F Miao, H Phan, J Wu - Molecules, 2019 - mdpi.com
We report a new boron dipyrromethene (BODIPY)-bridged bisphenoxyl diradicaloid (2),
which showed closed-shell diamagnetic character in less polar solvents such as …

[HTML][HTML] The Suzuki–Miyaura reaction as a tool for modification of phenoxyl-nitroxyl radicals of the 4 H-imidazole N-oxide series

YA Ten, OG Salnikov, SA Amitina, DV Stass… - RSC …, 2018 - pubs.rsc.org
2-(3, 5-Di-tert-butyl-4-hydroxyphenyl)-5-(4-iodophenyl)-4, 4-dimethyl-4H-imidazole 3-oxide
reacts with phenylboronic acid and its substituted derivatives in a cross-coupling reaction of …

[PDF][PDF] Crystal structure and fluorescence of 1-[8-phenyl-9-(phenylethynyl)-4H-benzo [def] carbazol-4-yl] ethan-1-one

HC Hsiao, PL Chen, SC Chuang - Acta Crystallographica Section …, 2022 - journals.iucr.org
The crystal of the title compound, C60H38N2O2, which crystallizes in the monoclinic space
group P21/n, was obtained by thermal evaporation of a 1: 1 dichloromethane and hexanes …