Racemisation in chemistry and biology

A Ballard, S Narduolo, HO Ahmed… - … A European Journal, 2020 - Wiley Online Library
The two enantiomers of a compound often have profoundly different biological properties
and thus their liability to racemisation in aqueous solutions is an important piece of …

In silico and in vivo hepatoprotective activity of the synthesized 5-benzylidene-2-thiohydantoin against diethylnitrosamine-induced liver injury in a rat model

LS Akree, ZA Amin, HO Ahmad - Scientific Reports, 2023 - nature.com
In the present study, the hepatoprotective effect of 5-benzylidine-2-thiohydantoin (5B2T), a
unique derivative of the thiohydantoin group, on liver injury induced by diethylnitrosamine …

The problem of racemization in drug discovery and tools to predict it

A Ballard, S Narduolo, HO Ahmad… - Expert opinion on …, 2019 - Taylor & Francis
Introduction: Racemization has long been an ignored risk in drug development, probably
because of a lack of convenient access to good tools for its detection and an absence of …

Quantitative prediction of rate constants for aqueous racemization to avoid pointless stereoselective syntheses

A Ballard, HO Ahmad, S Narduolo, L Rosa… - Angewandte …, 2018 - Wiley Online Library
Racemization has a large impact upon the biological properties of molecules but the
chemical scope of compounds with known rate constants for racemization in aqueous …

[HTML][HTML] A Computational DFT Study of the Stereoinversion of Succinimide Residues Formed in Proteins and Peptides Catalyzed by a Hydrogen Phosphate Ion: An …

O Takahashi - Symmetry, 2024 - mdpi.com
Succinimide residues formed spontaneously from aspartic acid (Asp) and asparagine (Asn)
residues in proteins and peptides are stereochemically unstable, undergoing partial l-to-d …

Hepatoprotective perspective of newly synthesized 3-(3, 5-bis (tri fluoro methyl) phenyl)-5-methyl-1-((1-methyl-1h-pyrrol-2-yl) methyl)-2-thioxoimidazolidin-4-one …

LS Akree, HO Ahmad, ZA Amin - Bulletin of the Chemical Society of …, 2024 - ajol.info
The hepatoprotective effect of synthesized 3-(3, 5-bis (trifluoromethyl) phenyl)-5-methyl-1-((1-
methyl-1H-pyrrol-2-yl) methyl)-2-thioxoimidazolidin-4-one (3FL-M) was evaluated against …

[PDF][PDF] Synthesis, computational study, and antibacterial activity of rhodanine and thiazolidine-2, 4-dione scaffolds

RQ Amin, HO Ahmad - Zanco J. Pure Appl. Sci, 2020 - iasj.net
In this research, different thiazolidine-2, 4-dione and 2-thioxothiazolidin-4-one derivatives (1-
13) have been synthesized by Knoevenagel Condensation (1-13). Thiazolidine-2, 4-dione …

[PDF][PDF] Angewandte

A Ballard, HO Ahmad, S Narduolo, L Rosa, N Chand… - researchgate.net
Racemization has a large impact upon the biological properties of molecules but the
chemical scope of compounds with known rate constants for racemization in aqueous …