The rise and current status of polaritonic photochemistry and photophysics
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
Manipulating matter by strong coupling to vacuum fields
FJ Garcia-Vidal, C Ciuti, TW Ebbesen - Science, 2021 - science.org
BACKGROUND One of the most important phenomena in cavity quantum electrodynamics
(cQED) is the so-called strong coupling regime, which appears when the interaction …
(cQED) is the so-called strong coupling regime, which appears when the interaction …
Chemistry under vibrational strong coupling
K Nagarajan, A Thomas… - Journal of the American …, 2021 - ACS Publications
Over the past decade, the possibility of manipulating chemistry and material properties using
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …
Understanding polaritonic chemistry from ab initio quantum electrodynamics
In this review, we present the theoretical foundations and first-principles frameworks to
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …
Ultrastrong coupling between light and matter
Ultrastrong coupling between light and matter has, in the past decade, transitioned from a
theoretical idea to an experimental reality. It is a new regime of quantum light–matter …
theoretical idea to an experimental reality. It is a new regime of quantum light–matter …
[HTML][HTML] Cavity frequency-dependent theory for vibrational polariton chemistry
Recent experiments demonstrate the control of chemical reactivities by coupling molecules
inside an optical microcavity. In contrast, transition state theory predicts no change of the …
inside an optical microcavity. In contrast, transition state theory predicts no change of the …
[HTML][HTML] Polariton chemistry: controlling molecular dynamics with optical cavities
Molecular polaritons are the optical excitations which emerge when molecular transitions
interact strongly with confined electromagnetic fields. Increasing interest in the hybrid …
interact strongly with confined electromagnetic fields. Increasing interest in the hybrid …
Light–matter interactions with photonic quasiparticles
Interactions between light and matter play an instrumental role in spectroscopy, sensing,
quantum information processing and lasers. In most of these applications, light is considered …
quantum information processing and lasers. In most of these applications, light is considered …
[HTML][HTML] Strong light–matter interactions: a new direction within chemistry
It is possible to modify the chemical and physical properties of molecules, not only through
chemical modifications but also by coupling molecules strongly to light. More intriguingly …
chemical modifications but also by coupling molecules strongly to light. More intriguingly …
Tilting a ground-state reactivity landscape by vibrational strong coupling
A Thomas, L Lethuillier-Karl, K Nagarajan… - Science, 2019 - science.org
Many chemical methods have been developed to favor a particular product in
transformations of compounds that have two or more reactive sites. We explored a different …
transformations of compounds that have two or more reactive sites. We explored a different …