The rise and current status of polaritonic photochemistry and photophysics

R Bhuyan, J Mony, O Kotov, GW Castellanos… - Chemical …, 2023 - ACS Publications
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …

Manipulating matter by strong coupling to vacuum fields

FJ Garcia-Vidal, C Ciuti, TW Ebbesen - Science, 2021 - science.org
BACKGROUND One of the most important phenomena in cavity quantum electrodynamics
(cQED) is the so-called strong coupling regime, which appears when the interaction …

Chemistry under vibrational strong coupling

K Nagarajan, A Thomas… - Journal of the American …, 2021 - ACS Publications
Over the past decade, the possibility of manipulating chemistry and material properties using
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …

Understanding polaritonic chemistry from ab initio quantum electrodynamics

M Ruggenthaler, D Sidler, A Rubio - Chemical Reviews, 2023 - ACS Publications
In this review, we present the theoretical foundations and first-principles frameworks to
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …

Ultrastrong coupling between light and matter

A Frisk Kockum, A Miranowicz, S De Liberato… - Nature Reviews …, 2019 - nature.com
Ultrastrong coupling between light and matter has, in the past decade, transitioned from a
theoretical idea to an experimental reality. It is a new regime of quantum light–matter …

[HTML][HTML] Cavity frequency-dependent theory for vibrational polariton chemistry

X Li, A Mandal, P Huo - Nature communications, 2021 - nature.com
Recent experiments demonstrate the control of chemical reactivities by coupling molecules
inside an optical microcavity. In contrast, transition state theory predicts no change of the …

[HTML][HTML] Polariton chemistry: controlling molecular dynamics with optical cavities

RF Ribeiro, LA Martínez-Martínez, M Du… - Chemical …, 2018 - pubs.rsc.org
Molecular polaritons are the optical excitations which emerge when molecular transitions
interact strongly with confined electromagnetic fields. Increasing interest in the hybrid …

Light–matter interactions with photonic quasiparticles

N Rivera, I Kaminer - Nature Reviews Physics, 2020 - nature.com
Interactions between light and matter play an instrumental role in spectroscopy, sensing,
quantum information processing and lasers. In most of these applications, light is considered …

[HTML][HTML] Strong light–matter interactions: a new direction within chemistry

M Hertzog, M Wang, J Mony, K Börjesson - Chemical Society Reviews, 2019 - pubs.rsc.org
It is possible to modify the chemical and physical properties of molecules, not only through
chemical modifications but also by coupling molecules strongly to light. More intriguingly …

Tilting a ground-state reactivity landscape by vibrational strong coupling

A Thomas, L Lethuillier-Karl, K Nagarajan… - Science, 2019 - science.org
Many chemical methods have been developed to favor a particular product in
transformations of compounds that have two or more reactive sites. We explored a different …