Porous organic cages: soluble, modular and molecular pores

T Hasell, AI Cooper - Nature Reviews Materials, 2016 - nature.com
Porosity is a rare property for molecular materials but, surprisingly, porous solids built from
discrete organic cage molecules have emerged as a versatile functional-materials platform …

Engineering single-atom sites into pore-confined nanospaces of porphyrinic metal–organic frameworks for the highly efficient photocatalytic hydrogen evolution …

Q Mo, L Zhang, S Li, H Song, Y Fan… - Journal of the American …, 2022 - ACS Publications
As a type of heterogeneous catalyst expected for the maximum atom efficiency, a series of
single-atom catalysts (SACs) containing spatially isolated metal single atoms (M-SAs) have …

Emission-tunable soft porous organic crystal based on squaraine for single-crystal analysis of guest-induced gate-opening transformation

L Li, H Ma, J Zhang, E Zhao, J Hao… - Journal of the …, 2021 - ACS Publications
Soft porous crystals (SPCs) with both crystallinity and flexibility have evolved as emerging
materials for lots of applications. However, the development of purely organic SPCs …

Perspectives on NMR studies of CO2 adsorption

D Bernin, N Hedin - Current Opinion in Colloid & Interface Science, 2018 - Elsevier
There is a consensus about a long-term goal of a carbon-neutral energy cycle, but the CO 2
emissions to the atmosphere are currently very large. Carbon Capture and Storage (CCS) …

Nitric oxide (NO) as a reagent for topochemical framework transformation and controlled NO release in covalent organic frameworks

ST Emmerling, J Maschita… - Journal of the American …, 2023 - ACS Publications
Covalent organic frameworks (COFs) have emerged as versatile platforms for the separation
and storage of hazardous gases. Simultaneously, the synthetic toolbox to tackle the “COF …

Efficient separation of C 2 hydrocarbons in a permanently porous hydrogen-bonded organic framework

TU Yoon, SB Baek, D Kim, EJ Kim, WG Lee… - Chemical …, 2018 - pubs.rsc.org
A highly robust porous hydrogen-bonded organic framework (HOF) constructed by 4, 4′,
4′′-benzene-1, 3, 5-triyl-tris (benzoic acid) not only achieves the highest uptakes of …

CO2 Adsorption in a Robust Iron(III) Pyrazolate‐Based MOF: Molecular‐Level Details and Frameworks Dynamics From Powder X‐ray Diffraction Adsorption …

R Vismara, S Terruzzi, A Maspero, T Grell… - Advanced …, 2024 - Wiley Online Library
Understanding adsorption processes at the molecular level, with multi‐technique
approaches, is nowadays at the frontier of porous materials research. In this work it is shown …

Guest exchange through facilitated transport in a seemingly impenetrable hydrogen-bonded framework

Y Li, M Handke, YS Chen… - Journal of the …, 2018 - ACS Publications
A new inclusion compound consisting of a guanidinium 1, 3, 5-tri (4-sulfophenyl) benzene
(G3TSPHB) host framework containing isophorone guests that surround isolated and …

Porous metal–organic polyhedra: morphology, porosity, and guest binding

SP Argent, I Da Silva, A Greenaway, M Savage… - Inorganic …, 2020 - ACS Publications
Designing porous materials which can selectively adsorb CO2 or CH4 is an important
environmental and industrial goal which requires an understanding of the host–guest …

[HTML][HTML] Deciphering the role of Cu0 and Cuσ+ in engendering the hydrogen production from glycerol reforming over Cu/CeO2: The effect of different Cu precursors

ACM Loy, WL Ng, J Ma, MH Uddin, J Vongsvivut… - Applied Catalysis B …, 2024 - Elsevier
Copper-based catalysts have been widely reported as remarkable candidates in reforming
processes; however, they often suffer from poor stability, sintering, and deactivation over …