Organic carbonates as solvents in synthesis and catalysis

B Schaffner, F Schaffner, SP Verevkin… - Chemical …, 2010 - ACS Publications
A solvent is one key component in a chemical transformation. As a reaction medium it
controls the interactions between reaction partners through heat transfer and intermolecular …

Predictive molecular thermodynamic models for liquid solvents, solid salts, polymers, and ionic liquids

Z Lei, B Chen, C Li, H Liu - Chemical reviews, 2008 - ACS Publications
Generally, molecular thermodynamic models for treating the phase equilibria of solutions
can be classified into two categories: activity coefficient relations and equations of state. The …

(p, Vm, T, x) measurements of dimethyl carbonate+ octane binary mixtures: I. Experimental results, isothermal compressibilities, isobaric expansivities and internal …

L Lugo, MJP Comuñas, ER López, J Fernández - Fluid phase equilibria, 2001 - Elsevier
Experimental densities for the compressed liquid phase are reported for dimethyl carbonate
and octane, and nine of their mixtures over the composition range (0.1≤ x≤ 0.9), the …

An exact quasi-chemical equation for excess heat capacity with W-shaped concentration dependence

JC Cobos - Fluid phase equilibria, 1997 - Elsevier
A reliable equation for the excess heat capacity CVE at constant volume is derived from
Guggenheim's quasi-chemical lattice theory of liquid mixtures for the case of equal-sized …

Thermodynamics of liquid mixtures containing a very strongly polar compound: Part 6. DISQUAC characterization of N, N-dialkylamides

JA González, JC Cobos, IG de la Fuente - Fluid phase equilibria, 2004 - Elsevier
Systems of N, N di (n-alkylamides)(hereafter, N, N-dialkylamides) with alkane, benzene,
toluene, 1-alkanol or 1-alkyne have been investigated in the framework of the DISQUAC …

Thermodynamics of mixtures containing alkoxyethanols. Part XV. DISQUAC characterization of systems of alkoxyethanols with n-alkanes or cyclohexane

JA González, JC Cobos, FJ Carmona… - Physical Chemistry …, 2001 - pubs.rsc.org
Binary mixtures of alkoxyethanols, CH3–(CH2) n–O–(CH2CH2O) mOH, and n-alkanes or
cyclohexane are characterized in terms of DISQUAC. The corresponding dispersive (DIS) …

Thermodynamics of organic mixtures containing amines. IV. Systems with aniline

JA González, I Mozo… - Canadian journal of …, 2005 - cdnsciencepub.com
Étude de mélanges binaires d'aniline en présence de benzène, de toluène, d'alcane,
d'alcanol et de N, N-dialkylamide dans le contexte du modèle DISQUAC. Les paramètres …

Thermodynamics of mixtures containing a very strongly polar compound. Part I. Experimental phase equilibria (solid–liquid and liquid–liquid) for sulfolane+ alkan-1 …

JA Gonzalez, U Domanska - Physical Chemistry Chemical Physics, 2001 - pubs.rsc.org
Equilibrium temperatures for liquid–liquid and solid–liquid transitions of systems containing
sulfolane and propan-1-ol, butan-1-ol, octan-1-ol or tetradecan-1-ol were measured by a …

Proximity effects and cyclization in oxaalkanes+ CCl4 mixtures DISQUAC characterization of the Cl–O interactions. Comparison with Dortmund UNIFAC results

JA González, IG de la Fuente, JC Cobos - Fluid phase equilibria, 1999 - Elsevier
Thermodynamic properties, vapor–liquid equilibria (VLE), molar excess Gibbs energies
(GE), molar excess enthalpies (HE) and natural logarithms of activity coefficients at infinite …

Correlation and prediction of excess molar enthalpies using DISQUAC

JA González, IG de la Fuente, JC Cobos - 2017 - books.rsc.org
The design of separation processes is based on the solution of the equations for material
and enthalpy balances. For this, a reliable knowledge of the real behaviour of …