Microstructural and dynamical heterogeneities in ionic liquids

YL Wang, B Li, S Sarman, F Mocci, ZY Lu… - Chemical …, 2020 - ACS Publications
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …

Structure and nanostructure in ionic liquids

R Hayes, GG Warr, R Atkin - Chemical reviews, 2015 - ACS Publications
Much of chemistry is concerned with the study of reactions and processes in solution, that is,
where liquids are used as solvents. 2, 3 The solvent is the (excess) liquid phase in which …

Ionic liquid crystals: versatile materials

K Goossens, K Lava, CW Bielawski… - Chemical …, 2016 - ACS Publications
This Review covers the recent developments (2005–2015) in the design, synthesis,
characterization, and application of thermotropic ionic liquid crystals. It was designed to give …

Targeted modifications in ionic liquids–from understanding to design

F Philippi, T Welton - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
Ionic liquids are extremely versatile and continue to find new applications in academia as
well as industry. This versatility is rooted in the manifold of possible ion types, ion …

Modern room temperature ionic liquids, a simple guide to understanding their structure and how it may relate to dynamics

JC Araque, JJ Hettige, CJ Margulis - The Journal of Physical …, 2015 - ACS Publications
Modern room temperature ionic liquids are structurally defined by symmetries on different
length scales. Polar–apolar alternation defines their nanoscale structural heterogeneity …

Solvent nanostructure, the solvophobic effect and amphiphile self-assembly in ionic liquids

TL Greaves, CJ Drummond - Chemical Society Reviews, 2013 - pubs.rsc.org
The ability of ionic liquids (ILs) to support amphiphile self-assembly into a range of
mesophase structures has been established as a widespread phenomenon. From the ILs …

Domain Analysis in Nanostructured Liquids: A Post‐Molecular Dynamics Study at the Example of Ionic Liquids

M Brehm, H Weber, M Thomas, O Hollóczki… - …, 2015 - Wiley Online Library
In the present computational work, we develop a new tool for our trajectory analysis program
TRAVIS to analyze the well‐known behavior of liquids to separate into microphases. The …

Triphilic Ionic‐Liquid Mixtures: Fluorinated and Non‐fluorinated Aprotic Ionic‐Liquid Mixtures

O Hollóczki, M Macchiagodena, H Weber… - …, 2015 - Wiley Online Library
We present here the possibility of forming triphilic mixtures from alkyl‐and
fluoroalkylimidazolium ionic liquids, thus, macroscopically homogeneous mixtures for which …

Harnessing the Hybridization of a Metal‐Organic Framework and Superbase‐Derived Ionic Liquid for High‐Performance Direct Air Capture of CO2

L Qiu, L Peng, D Moitra, H Liu, Y Fu, Z Dong, W Hu… - Small, 2023 - Wiley Online Library
Direct air capture (DAC) of CO2 has emerged as the most promising “negative carbon
emission” technologies. Despite being state‐of‐the‐art, sorbents deploying alkali …

How does the ionic liquid organizational landscape change when nonpolar cationic alkyl groups are replaced by polar isoelectronic diethers?

HK Kashyap, CS Santos, RP Daly… - The Journal of …, 2013 - ACS Publications
X-ray scattering experiments and molecular dynamics simulations have been performed to
investigate the structure of four room temperature ionic liquids (ILs) comprising the bis …