Palladium (II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications

RI McDonald, G Liu, SS Stahl - Chemical reviews, 2011 - ACS Publications
The development of catalytic reactions of alkenes transformed the chemical industry in the
mid-20th century. Representative reactions included hydrogenation, oxidation …

Carbon–heteroatom bond formation catalysed by organometallic complexes

JF Hartwig - Nature, 2008 - nature.com
At one time the synthetic chemist's last resort, reactions catalysed by transition metals are
now the preferred method for synthesizing many types of organic molecule. A recent …

[图书][B] Modern fluoroorganic chemistry: synthesis, reactivity, applications

P Kirsch - 2006 - books.google.com
In this handbook, Peer Kirsch clearly shows that this exciting field is no longer an exotic area
of research. Aimed primarily at synthetic chemists wanting to gain a deeper understanding of …

Catalytic enantioselective functionalization of unactivated terminal alkenes

JR Coombs, JP Morken - Angewandte Chemie International …, 2016 - Wiley Online Library
Terminal alkenes are readily available functional groups which appear in α‐olefins
produced by the chemical industry, and they appear in the products of many contemporary …

The Wacker reaction and related alkene oxidation reactions

JM Takacs, XT Jiang - Current Organic Chemistry, 2003 - benthamdirect.com
The objective of this review is to survey the current state of the Wacker and related alkene
oxidation reactions focusing on the reactions of higher alkenes and emphasizing the …

Two-Faced Reactivity of Alkenes:  cis- versus trans-Aminopalladation in Aerobic Pd-Catalyzed Intramolecular Aza-Wacker Reactions

G Liu, SS Stahl - Journal of the American Chemical Society, 2007 - ACS Publications
A number of different PdII catalyst systems have been reported recently for the Wacker-type
aerobic oxidative cyclization of alkenes bearing tethered nitrogen nucleophiles. This study …

Oxidative cyclizations in a nonpolar solvent using molecular oxygen and studies on the stereochemistry of oxypalladation

RM Trend, YK Ramtohul, BM Stoltz - Journal of the American …, 2005 - ACS Publications
Oxidative cyclizations of a variety of heteroatom nucleophiles onto unactivated olefins are
catalyzed by palladium (II) and pyridine in the presence of molecular oxygen as the sole …

Recent progress in Wacker oxidations: moving toward molecular oxygen as the sole oxidant

CN Cornell, MS Sigman - Inorganic chemistry, 2007 - ACS Publications
Wacker oxidations, the conversion of terminal olefins to methyl ketones with Pd (II) catalysts,
have seen widespread use in synthetic applications. Standard synthetic Wacker conditions …

Aldehydes from Pd-catalysed oxidation of terminal olefins

J Muzart - Tetrahedron, 2007 - Elsevier
The PdII-catalysed oxidation of alkenes to carbonyl compounds, usually referred to as the
Wacker reaction, 1, 2 is one of the most well-known reactions mediated by palladium, and …

Palladium-catalysed reactions of alcohols. Part C: Formation of ether linkages

J Muzart - Tetrahedron, 2005 - Elsevier
The literature contains an impressive number of Pdcatalysed reactions using alcohols as
substrates or reagents, and we are attempting to cover this topic with a series of reviews …