Toolbox for distal C–H bond functionalizations in organic molecules
Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …
Visible light-induced organophotoredox-catalyzed difunctionalization of alkenes and alkynes
S Gupta, A Kundu, S Ghosh, A Chakraborty… - Green Chemistry, 2023 - pubs.rsc.org
In the era of organic synthesis, the direct difunctionalization strategies of alkenes and
alkynes are very eminent, which open up an excellent route to introduce two functional …
alkynes are very eminent, which open up an excellent route to introduce two functional …
Nickel-catalyzed dicarbofunctionalization of alkenes
X Qi, T Diao - ACS catalysis, 2020 - ACS Publications
1, 2-Dicarbofunctionalization of alkenes has emerged as an efficient synthetic strategy for
preparing substituted molecules by coupling readily available alkenes with electrophiles …
preparing substituted molecules by coupling readily available alkenes with electrophiles …
Nickel chain-walking catalysis: a journey to migratory carboboration of alkenes
Y Li, G Yin - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Chain-walking offers extensive opportunities for innovating synthetic methods
that involve constructing chemical bonds at unconventional sites. This approach provides …
that involve constructing chemical bonds at unconventional sites. This approach provides …
The interplay of carbophilic activation and Au (I)/Au (III) catalysis: an emerging technique for 1, 2-difunctionalization of C–C multiple bonds
Gold complexes have emerged as the catalysts of choice for various functionalization
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …
Intermolecular radical carboamination of alkenes
H Jiang, A Studer - Chemical Society Reviews, 2020 - pubs.rsc.org
Vicinal alkene carboamination is a highly efficient and practical synthetic strategy for the
straightforward preparation of diverse and valuable amine derivatives starting from simple …
straightforward preparation of diverse and valuable amine derivatives starting from simple …
Copper-catalyzed radical relay for asymmetric radical transformations
F Wang, P Chen, G Liu - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus The direct transformation of C–H bonds into diverse functional groups
represents one of the most atom-and step-economical strategies for organic synthesis and …
represents one of the most atom-and step-economical strategies for organic synthesis and …
Recent developments on 1, 2-difunctionalization and hydrofunctionalization of unactivated alkenes and alkynes involving C–S bond formation
B Dong, J Shen, LG Xie - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
Alkenes and alkynes are feedstock compounds and key units in many natural products,
pharmaceuticals, agrochemicals, and organic functional materials. Hydrofunctionalization …
pharmaceuticals, agrochemicals, and organic functional materials. Hydrofunctionalization …
Asymmetric Ni-catalyzed radical relayed reductive coupling
X Wei, W Shu, A García-Domínguez… - Journal of the …, 2020 - ACS Publications
Alkene dicarbofunctionalizations enable the streamlined construction of aliphatic structures
and have thus been the subject of intense research efforts. Despite significant progress …
and have thus been the subject of intense research efforts. Despite significant progress …
Photoredox cooperative N-heterocyclic carbene/palladium-catalysed alkylacylation of alkenes
YF Han, Y Huang, H Liu, ZH Gao, CL Zhang… - Nature …, 2022 - nature.com
Three-component carboacylation of simple alkenes with readily available reagents is
challenging. Transition metal-catalysed intermolecular carboacylation works for alkenes with …
challenging. Transition metal-catalysed intermolecular carboacylation works for alkenes with …