The build-up of polymetallic supermolecules based on porphyrins and ruthenium bipyridine
complexes has been pursued with great interest. A relevant series of symmetric polynuclear …

Lead has been used as a heavy atom derivative to solve the phase problem in the crystal
structures of a variety of protein including the calcium proteins calmodulin and …

Supramolecular chemistry is expected to keep a high developing pace in the next years,
giving support to the advancement of molecular devices and nanotechnology. In this sense …

The chemistry of μ-oxo-centered trinuclear ruthenium-carboxylate clusters, of general
formula [Ru3O (RCO2) 6L3] n, has been dealt with special emphasis on their spectroscopic …

The properties of the trinuclear cluster [Ru3OAc6 (pic) 2 (NO)] PF6 (pic= 4-methyl pyridine,
Ac= acetate ion) and the photochemical behavior of the corresponding molecular films are …

Supramolecular chemistry deals with the association of several chemical species, in an
organized way and according to well defined purposes. Based on a molecular engineering …

The synthesis and characterization of a zinc meso‐tetra (4‐pyridyl) porphyrin containing four
coordinated µ3‐oxo‐triruthenium acetate cluster complexes, ZnTCP, are reported. The …

The binding of NO to the trinuclear cluster [Ru3O (CH3CO2) 6 (py) 2]+(py= pyridine) leads to
a stable, diamagnetic [Ru3O (CH3CO2) 6 (py) 2 (NO)]+ complex, displaying extended …

The synthesis and characterization of a new supermolecular porphyrin obtained by the
coordination of four pentacyanoferrate (II) groups to the pyridyl N-atoms of meso-(3-pyridyl) …

A terminal ligand-substitution reaction at triruthenium redox centres within monolayer films is
investigated. For this purpose, a new redox-active trinuclear ruthenium complex containing …