Photocatalysis is a powerful tool to assemble diverse chemical scaffolds, yet a bottleneck on
its further development is the understanding of the multitude of possible pathways when …

Iron, mostly as Fe2+ or Fe3+ bound in oxides, is the second most common element in the
earth's crust after aluminium. Salts of the d-block metal are cheap and commercially …

Water can accelerate a variety of organic reactions far beyond the rates observed in
classical organic solvents. However, using pure water as a solvent introduces solubility …

A visible-light-induced metal-free trifluoromethylselenolation of aryl iodides and bromides
with [Me4N][SeCF3] is described. The reaction was conducted at ambient temperature by …

A cascade reaction consisting of a Heck reaction followed by an enzyme-catalyzed reaction
is carried out in different aqueous solutions. In particular, the impact of the structuring of the …

Owing to their remarkable practicality and utility, phosphonium salts have attracted
substantial interest and are widely applied in critical areas, such as medicine, materials …

The many synthetic possibilities that arise when using radical intermediates, in place of their
polar counterparts, make contemporary radical chemistry research an exhilarating field. The …

An arylation of anions of active methylene compounds with aryl halides provides an access
to synthetically versatile α‐arylated 1, 3‐diketones, β‐keto esters, β‐keto nitriles, β‐cyano …

We report the catalytic generation of pyridyl radicals through photoexcitation of the electron
donor–acceptor (EDA) complex, which enables the C2-selective heteroarylation of indole …

Photoinduced aryl radical generation is a powerful strategy in organic synthesis that
facilitates the formation of diverse carbon‐carbon and carbon‐heteroatom bonds. The …