Polymer nanocomposite dielectrics: understanding the matrix/particle interface

S Wang, Z Luo, J Liang, J Hu, N Jiang, J He, Q Li - ACS nano, 2022 - ACS Publications
Polymer nanocomposite dielectrics possess exceptional electric properties that are absent
in the pristine dielectric polymers. The matrix/particle interface in polymer nanocomposite …

Dynamics of polymer segments, polymer chains, and nanoparticles in polymer nanocomposite melts: A review

EJ Bailey, KI Winey - Progress in Polymer Science, 2020 - Elsevier
The addition of nanoparticles (NPs) to a polymer matrix, forming a polymer nanocomposite
(PNC), is known to alter the microscopic dynamic processes of both species which leads to …

Silica–epoxy vitrimer nanocomposites

A Legrand, C Soulié-Ziakovic - Macromolecules, 2016 - ACS Publications
Reinforced silica–epoxy vitrimer nanocomposites have been made in a solvent-free, easily
processable, and economical way with filler contents up to 40 wt%. Increasing silica content …

Concepts and conflicts in nanoparticles reinforcement to polymers beyond hydrodynamics

Y Song, Q Zheng - Progress in Materials Science, 2016 - Elsevier
With substantial progresses in reinforcement mechanism of nanoparticle filled polymers
(NPFPs) beyond the hydrodynamic limit, now is the time to reconsider this topic …

Big effect of small nanoparticles: a shift in paradigm for polymer nanocomposites

S Cheng, SJ Xie, JMY Carrillo, B Carroll, H Martin… - ACS …, 2017 - ACS Publications
Polymer nanocomposites (PNCs) are important materials that are widely used in many
current technologies and potentially have broader applications in the future due to their …

[HTML][HTML] Network dynamics in nanofilled polymers

GP Baeza, C Dessi, S Costanzo, D Zhao… - Nature …, 2016 - nature.com
It is well accepted that adding nanoparticles (NPs) to polymer melts can result in significant
property improvements. Here we focus on the causes of mechanical reinforcement and …

Structural analyses of the bound rubber in silica-filled silicone rubber nanocomposites reveal mechanisms of filler-rubber interaction

L Huang, F Yu, Y Liu, A Lu, Z Song, W Liu… - … Science and Technology, 2023 - Elsevier
Although the reinforcing effect of fumed silica on silicone rubber is always better than that of
precipitated silica, their enhancement mechanism is still controversial due to the cognitive …

[HTML][HTML] Interaction between filler and polymeric matrix in nanocomposites: Magnetic approach and applications

M Bustamante-Torres, D Romero-Fierro… - Polymers, 2021 - mdpi.com
In recent years, polymer nanocomposites produced by combining nanofillers and a
polymeric matrix are emerging as interesting materials. Polymeric composites have a wide …

Controlling Interfacial Dynamics: Covalent Bonding versus Physical Adsorption in Polymer Nanocomposites

AP Holt, V Bocharova, S Cheng, AM Kisliuk, BT White… - ACS …, 2016 - ACS Publications
It is generally believed that the strength of the polymer–nanoparticle interaction controls the
modification of near-interface segmental mobility in polymer nanocomposites (PNCs) …

Unraveling the mechanism of nanoscale mechanical reinforcement in glassy polymer nanocomposites

S Cheng, V Bocharova, A Belianinov, S Xiong… - Nano …, 2016 - ACS Publications
The mechanical reinforcement of polymer nanocomposites (PNCs) above the glass
transition temperature, T g, has been extensively studied. However, not much is known …