Photochemical synthesis of anilines via Ni-catalyzed coupling of aryl halides with ammonium salts

G Song, DZ Nong, Q Li, Y Yan, G Li, J Fan… - ACS …, 2022 - ACS Publications
Easy, efficient, and economic synthesis of anilines remains an important challenge in
synthetic chemistry. In this study, a Ni (OAc) 2-bipyridine complex is shown to readily …

An integrated carbon nitride‐nickel photocatalyst for the amination of aryl halides using sodium azide

A Vijeta, C Casadevall, E Reisner - Angewandte Chemie, 2022 - Wiley Online Library
The synthesis of primary anilines via sustainable methods remains a challenge in organic
synthesis. We report a photocatalytic protocol for the selective synthesis of primary anilines …

Metal-free, rapid, and highly chemoselective reduction of aromatic nitro compounds at room temperature

M Jang, T Lim, BY Park, MS Han - The Journal of Organic …, 2022 - ACS Publications
In this study, we developed a metal-free and highly chemoselective method for the reduction
of aromatic nitro compounds. This reduction was performed using tetrahydroxydiboron [B2 …

Werner salt as nickel and ammonia source for photochemical synthesis of primary aryl amines

G Song, J Song, Q Li, DZ Nong, J Dong… - Angewandte …, 2024 - Wiley Online Library
Cheap, stable and easy‐to‐handle Werner ammine salts have been known for more than a
century; but they have been rarely used in organic synthesis. Herein, we report that the …

Photoexcitation of Distinct Divalent Palladium Complexes in Cross‐Coupling Amination Under Air

R Kancherla, K Muralirajan, S Dutta, K Pal… - Angewandte …, 2024 - Wiley Online Library
The development of metal complexes that function as both photocatalyst and cross‐coupling
catalyst remains a challenging research topic. So far, progress has been shown in palladium …

Copper-catalyzed C (aryl)–N bond formation

F Monnier, M Taillefer - Amination and Formation of sp2 CN Bonds, 2013 - Springer
Although requiring the use of stoichiometric amounts of metal and harsh conditions, the
copper-mediated coupling reactions of aryl halides with amines and phenols (Ullmann …

A palladium complex immobilized onto mesoporous silica: a highly efficient and reusable catalytic system for carbon–carbon bond formation and anilines synthesis

M Nikoorazm, N Noori, B Tahmasbi… - Transition Metal Chemistry, 2017 - Springer
A palladium complex supported on functionalized mesoporous silica MCM-41 proved to be
a highly efficient, recoverable catalyst for C–C coupling reactions and amination of aryl …

A new palladium complex supported on magnetic nanoparticles and applied as an catalyst in amination of aryl halides, Heck and Suzuki reactions

A Ghorbani-Choghamarani, B Tahmasbi… - Journal of the Iranian …, 2017 - Springer
A simple, efficient and less expensive protocol for the phosphine-free C–C coupling
reactions and synthesis of anilines in the presence of 2-aminobenzamide complex of …

Palladium 2‐mercapto‐N‐propylacetamide complex anchored onto MCM‐41 as efficient and reusable nanocatalyst for Suzuki, Stille and Heck reactions and …

M Nikoorazm… - Applied …, 2016 - Wiley Online Library
A palladium 2‐mercapto‐N‐propylacetamide complex supported on functionalized MCM‐41
was prepared by a post‐grafting method and considered as an efficient catalyst for C C …

Pd-grafted functionalized mesoporous MCM-41: a novel, green and heterogeneous nanocatalyst for the selective synthesis of phenols and anilines from aryl halides …

F Havasi, A Ghorbani-Choghamarani… - New Journal of …, 2015 - pubs.rsc.org
A new type of mesoporous-recoverable catalyst was synthesized by the immobilization of Pd
on the surface of functionalized mesoporous MCM-41 and used as an efficient, recoverable …