Organocatalysis in inert C–H bond functionalization
Y Qin, L Zhu, S Luo - Chemical reviews, 2017 - ACS Publications
As two coexisting and fast-growing research fields in modern synthetic chemistry, the
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …
Transition-metal-free coupling reactions
CL Sun, ZJ Shi - Chemical reviews, 2014 - ACS Publications
Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …
century and represent a great success in organic chemistry, along with the birth and growth …
Recent development of direct asymmetric functionalization of inert C–H bonds
C Zheng, SL You - RSC advances, 2014 - pubs.rsc.org
The area of direct asymmetric functionalization of inert C–H bonds has attracted
considerable attention in recent years. To realize this type of challenging but promising …
considerable attention in recent years. To realize this type of challenging but promising …
Cyclization Cascades via N-Amidyl Radicals toward Highly Functionalized Heterocyclic Scaffolds
N Fuentes, W Kong… - Journal of the …, 2015 - ACS Publications
The addition of a variety of radicals to the double bond of N-(arylsulfonyl) acrylamides can
trigger cyclization/aryl migration/desulfonylation cascades via amidyl radical intermediates …
trigger cyclization/aryl migration/desulfonylation cascades via amidyl radical intermediates …
Dioxygen-triggered oxidative radical reaction: direct aerobic difunctionalization of terminal alkynes toward β-keto sulfones
Q Lu, J Zhang, G Zhao, Y Qi, H Wang… - Journal of the American …, 2013 - ACS Publications
An unprecedented dioxygen-triggered oxidative radical process was explored using
dioxygen as the solely terminal oxidant, realizing aerobic oxidaitve difunctionalization of …
dioxygen as the solely terminal oxidant, realizing aerobic oxidaitve difunctionalization of …
Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant
Z Shi, C Zhang, C Tang, N Jiao - Chemical Society Reviews, 2012 - pubs.rsc.org
For green and sustainable chemistry, molecular oxygen is considered as an ideal oxidant
due to its natural, inexpensive, and environmentally friendly characteristics, and therefore …
due to its natural, inexpensive, and environmentally friendly characteristics, and therefore …
A Comparative Mechanistic Study of Cu-Catalyzed Oxidative Coupling Reactions with N-Phenyltetrahydroisoquinoline
E Boess, C Schmitz, M Klussmann - Journal of the American …, 2012 - ACS Publications
A comparative mechanistic study of Cu-catalyzed oxidative coupling reactions of N-
phenyltetrahydroisoquinoline with different nucleophiles was conducted. Two previously …
phenyltetrahydroisoquinoline with different nucleophiles was conducted. Two previously …
Asymmetric dearomatization of indole derivatives with N‐hydroxycarbamates enabled by photoredox catalysis
YZ Cheng, QR Zhao, X Zhang, SL You - Angewandte Chemie, 2019 - Wiley Online Library
Dearomatization of indoles provides efficient synthetic routes for substituted indolines. In
most cases, indoles serve as nucleophiles. Reported here is an asymmetric dearomatization …
most cases, indoles serve as nucleophiles. Reported here is an asymmetric dearomatization …
Cu-catalyzed esterification reaction via aerobic oxygenation and C–C bond cleavage: an approach to α-ketoesters
C Zhang, P Feng, N Jiao - Journal of the American Chemical …, 2013 - ACS Publications
The Cu-catalyzed novel aerobic oxidative esterification reaction of 1, 3-diones for the
synthesis of α-ketoesters has been developed. This method combines C–C σ-bond …
synthesis of α-ketoesters has been developed. This method combines C–C σ-bond …
A Versatile C–H Functionalization of Tetrahydroisoquinolines Catalyzed by Iodine at Aerobic Conditions†
A versatile aerobic catalytic system (I2 and O2/TBHP) for C–H functionalization is reported.
This CDC (cross-dehydrogentive coupling) reaction is compatible with a large number of …
This CDC (cross-dehydrogentive coupling) reaction is compatible with a large number of …