A review of catalytic partial oxidation of methane to synthesis gas with emphasis on reaction mechanisms over transition metal catalysts

BC Enger, R Lødeng, A Holmen - Applied Catalysis A: General, 2008 - Elsevier
Catalytic partial oxidation of methane has been reviewed with an emphasis on the reaction
mechanisms over transition metal catalysts. The thermodynamics and aspects related to …

IR spectroscopy in catalysis

J Ryczkowski - Catalysis Today, 2001 - Elsevier
Infrared (IR) spectroscopy undoubtedly represents one of the most important tools in
catalysis research. In this review, recent catalytic applications of the most popular IR …

Facile Cr3+-Doping Strategy Dramatically Promoting Ru/CeO2 for Low-Temperature CO2 Methanation: Unraveling the Roles of Surface Oxygen Vacancies and …

X Xu, L Liu, Y Tong, X Fang, J Xu, D Jiang… - ACS Catalysis, 2021 - ACS Publications
Cr cation doping in the support of the Ru/CeO2 catalyst with a Cr/Ce molar ratio of 1: 9
dramatically improved the CO2 methanation activity at low temperatures, with the turnover …

Resolving ruthenium: XPS studies of common ruthenium materials

DJ Morgan - Surface and Interface Analysis, 2015 - Wiley Online Library
X‐ray photoelectron spectroscopy (XPS) utilising monochromatic Al Kα radiation has been
employed to study metallic ruthenium and the catalytically and technologically important …

Electronic modulation of metal-support interactions improves polypropylene hydrogenolysis over ruthenium catalysts

PA Kots, T Xie, BC Vance, CM Quinn… - Nature …, 2022 - nature.com
Ruthenium (Ru) is the one of the most promising catalysts for polyolefin hydrogenolysis. Its
performance varies widely with the support, but the reasons remain unknown. Here, we …

Defects engineering simultaneously enhances activity and recyclability of MOFs in selective hydrogenation of biomass

W Xu, Y Zhang, J Wang, Y Xu, L Bian, Q Ju… - Nature …, 2022 - nature.com
The development of synthetic methodologies towards enhanced performance in biomass
conversion is desirable due to the growing energy demand. Here we design two types of Ru …

Controlling CO2 Hydrogenation Selectivity by Metal‐Supported Electron Transfer

X Li, J Lin, L Li, Y Huang, X Pan… - Angewandte Chemie …, 2020 - Wiley Online Library
Tuning CO2 hydrogenation selectivity to obtain targeted value‐added chemicals and fuels
has attracted increasing attention. However, a fundamental understanding of the way to …

Disentangling the size-dependent geometric and electronic effects of palladium nanocatalysts beyond selectivity

H Wang, XK Gu, X Zheng, H Pan, J Zhu, S Chen… - Science …, 2019 - science.org
The prominent size effect of metal nanoparticles shapes decisively nanocatalysis, but
entanglement of the corresponding geometric and electronic effects prevents exploiting their …

Electronic effect of ruthenium nanoparticles on efficient reductive amination of carbonyl compounds

T Komanoya, T Kinemura, Y Kita… - Journal of the …, 2017 - ACS Publications
Highly selective synthesis of primary amines over heterogeneous catalysts is still a
challenge for the chemical industry. Ruthenium nanoparticles supported on Nb2O5 act as a …

Tuning reactivity of Fischer–Tropsch synthesis by regulating TiOx overlayer over Ru/TiO2 nanocatalysts

Y Zhang, X Yang, X Yang, H Duan, H Qi, Y Su… - Nature …, 2020 - nature.com
Abstract The activity of Fischer–Tropsch synthesis (FTS) on metal-based nanocatalysts can
be greatly promoted by the support of reducible oxides, while the role of support remains …