Advancing next-generation polymers: Through self-strengthening via mechanochemistry

Y Zhao, X Guo, F Gao, C Fu, L Shen, J Ma - European Polymer Journal, 2024 - Elsevier
Force-responsive, self-strengthening polymers refer to those that, under the stimulus of
mechanical forces, have mechanophore groups capable of reacting with additives or …

Synthesis of Metal–Organic Cages via Orthogonal Bond Cleavage in 3D Metal–Organic Frameworks

S Ruiz-Relaño, D Nam, J Albalad… - Journal of the …, 2024 - ACS Publications
Herein we address the question of whether a supramolecular finite metal–organic structure
such as a cage or metal–organic polyhedron (MOP) can be synthesized via controlled …

The Restoring Force Triangle: A Mnemonic Device for Polymer Mechanochemistry

Y Sun, F Xie, JS Moore - Journal of the American Chemical …, 2024 - ACS Publications
In polymer mechanochemistry, mechanophores are specific molecular units within the
macromolecular backbone that are particularly sensitive to tension. To facilitate …

Force-Activated Spin-Crossover in Fe2+ and Co2+ Transition Metal Mechanophores

X Huang, I Kevlishvili, SL Craig, HJ Kulik - Inorganic Chemistry, 2024 - ACS Publications
Transition metal mechanophores exhibiting force-activated spin-crossover are attractive
design targets, yet large-scale discovery of them has not been pursued due in large part to …

Mechanochemical Release of 9, 10-Diphenylanthracene via Flex-Activation of Its 1, 4-Diels–Alder Adduct

H Hu, L Meng, Y Zhou, Y Chen, Y Zhou, B Xi… - ACS Macro …, 2024 - ACS Publications
Flex-activated mechanophores capable of releasing small molecules utilize bond bending to
facilitate their mechanochemical activation without compromising the overall …

[HTML][HTML] Research on the Production of Hydrogen Fluoride from Silicon Tetrafluoride Using 2.45 GHz Microwave Plasma

S Liu, L Shi, G Liu, W Xiao, H Zhu - Processes, 2024 - mdpi.com
Silicon tetrafluoride (SiF4), being a toxic gas, contains abundant fluorine and silicon
resources. However, at present, the extraction of these resources from SiF4 remains a …

Mechanochemical generation of nitrogen-centred radicals for the formation of tertiary amines in polymers

S Storch, D Campagna, S Aydonat, R Göstl - RSC Mechanochemistry, 2025 - pubs.rsc.org
Force-activated functional groups in polymers may inform the design of future smart
materials in which mechanical events trigger productive chemistry. The availability of such …