Review of Fe-based spin crossover metal complexes in multiscale device architectures

N Amin, SM Said, MFM Salleh, AM Afifi, N Ibrahim… - Inorganica Chimica …, 2023 - Elsevier
Metal complexes involving d 4-d 7 first-row transition metals exhibit spin-crossover (SCO)
behaviour between low-spin and high-spin states in response to external stimuli such as …

Recent advances in single-molecule sensors based on STM break junction measurements

SL Lv, C Zeng, Z Yu, JF Zheng, YH Wang, Y Shao… - Biosensors, 2022 - mdpi.com
Single-molecule recognition and detection with the highest resolution measurement has
been one of the ultimate goals in science and engineering. Break junction techniques …

Strongly Hydrogen-Bonded Networks Formed by Sulfate and Bisulfate Salts of Benzenetetramines

JOE Sosoe, T Maris, JD Wuest - Crystal Growth & Design, 2023 - ACS Publications
Benzenetetramines, like other aromatic compounds with multiple NH2 groups, are easily
oxidized and are attractive candidates for use as components of redox-active organic …

Experimental observation of the role of countercations in modulating the electrical conductance of Preyssler-type polyoxometalate nanodevices

C Huez, S Renaudineau, F Volatron, A Proust… - Nanoscale, 2023 - pubs.rsc.org
Polyoxometalates are nanoscale molecular oxides with promising properties that are
currently explored for molecule-based memory devices. In this work, we synthesize a series …

Toward Practical Single‐Molecule/Atom Switches

X Xu, C Gao, R Emusani, C Jia, D Xiang - Advanced Science, 2024 - Wiley Online Library
Electronic switches have been considered to be one of the most important components of
contemporary electronic circuits for processing and storing digital information. Fabricating …

Electrical monitoring of single-event protonation dynamics at the solid-liquid interface and its regulation by external mechanical forces

C Zhao, J Diao, Z Liu, J Hao, S He, S Li, X Li… - Nature …, 2024 - nature.com
Detecting chemical reaction dynamics at solid-liquid interfaces is important for
understanding heterogeneous reactions. However, there is a lack of exploration of interface …

Bias‐triggered conductivity switching and high effective rectification in metallocene‐based molecular junctions

A Asyuda, S Das, H Lang, E Zojer… - Advanced Electronic …, 2022 - Wiley Online Library
Molecular diodes usually exhibit fixed current values at a specific bias and achieve sizable
rectification ratio (RR) at voltages of≈ 1.0 V. Here, a series of custom‐designed molecular …

Oxazine: an anchoring group serving as functional kernels to construct single-molecule switches

S Li, Y Jiang, Y Wang, D Lin, H Pan, Y Wang… - Journal of Materials …, 2024 - pubs.rsc.org
As a central research target in molecular electronics, molecular switches have been
extensively explored over the past decades. We theoretically demonstrate that when linking …

Refreshing the Legacy of Rudolf Nietzki: Benzene-1, 2, 4, 5-tetramine and Related Compounds

JOE Sosoe, C Malveau, T Maris, R Iftimie… - The Journal of Organic …, 2023 - ACS Publications
Like hydroquinones and quinones, aromatic compounds with multiple NH2 groups and the
corresponding quinonediimines have the potential to serve as components of useful redox …

Hydrazone Molecular Switches with Paramagnetic Center as 19F Magnetic Resonance Imaging Relaxation Enhancement Agents for pH Imaging

D Janasik, K Jasiński, J Szreder, WP Węglarz… - ACS …, 2023 - ACS Publications
The design and synthesis of hydrazone-based switches with a CF3 reporting group for 19F
pH imaging using relaxation rate changes were described. A paramagnetic center was …