Gold-catalyzed reactions of specially activated alkynes, allenes, and alkenes

D Campeau, DF León Rayo, A Mansour… - Chemical …, 2020 - ACS Publications
This review describes the gold-catalyzed reactions of specially activated alkynes, allenes,
and alkenes. Such species are characterized by the presence of either electron-donating or …

The interplay of carbophilic activation and Au (I)/Au (III) catalysis: an emerging technique for 1, 2-difunctionalization of C–C multiple bonds

VW Bhoyare, AG Tathe, A Das, CC Chintawar… - Chemical Society …, 2021 - pubs.rsc.org
Gold complexes have emerged as the catalysts of choice for various functionalization
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …

Recent advances in gold (III) chemistry: structure, bonding, reactivity, and role in homogeneous catalysis

L Rocchigiani, M Bochmann - Chemical Reviews, 2020 - ACS Publications
Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Optimizing catalyst and reaction conditions in gold (I) catalysis–ligand development

A Collado, DJ Nelson, SP Nolan - Chemical Reviews, 2021 - ACS Publications
This review considers phosphine and N-heterocyclic carbene complexes of gold (I) that are
used as (pre) catalysts for a range of reactions in organic synthesis. These are divided …

Photoinduced gold-catalyzed divergent dechloroalkylation of gem-dichloroalkanes

CL Ji, J Han, T Li, CG Zhao, C Zhu, J Xie - Nature Catalysis, 2022 - nature.com
The use of alkyl chlorides as C (sp 3)-hybridized electrophiles for the construction of C (sp 3)–
C (sp 3) bonds represents one of the most challenging issues in organic synthesis …

Recent advances in metal‐catalyzed functionalization of indoles

K Urbina, D Tresp, K Sipps… - Advanced Synthesis & …, 2021 - Wiley Online Library
Indole is one of the most important heterocycles in organic synthesis, natural products, and
drug discovery. Recently, tremendous advances in the selective functionalization of indoles …

Main avenues in gold coordination chemistry

RP Herrera, MC Gimeno - Chemical Reviews, 2021 - ACS Publications
In this contribution, we provide an overview of the main avenues that have emerged in gold
coordination chemistry during the last years. The unique properties of gold have motivated …

Site-selective arylation of carboxamides from unprotected peptides

W Li, Y Chen, Y Chen, S Xia, W Chang… - Journal of the …, 2023 - ACS Publications
The amidated peptides are an important class of biologically active compounds due to their
unique biological properties and wide applications as potential peptide drugs and …

Dinuclear gold catalysis

W Wang, CL Ji, K Liu, CG Zhao, W Li… - Chemical Society Reviews, 2021 - pubs.rsc.org
Gold chemistry has developed extensively in the past decade, and a dozen good reviews
have been presented discussing this progress. Few however have paid close attention to …

Gold-catalyzed heck reaction

VW Bhoyare, ED Sosa Carrizo… - Journal of the …, 2023 - ACS Publications
Herein, we report a gold-catalyzed Heck reaction facilitated by the ligand-enabled Au (I)/Au
(III) redox catalysis. The elementary organometallic steps such as migratory insertion and β …