Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

Metal-involving synthesis and reactions of oximes

DS Bolotin, NA Bokach, MY Demakova… - Chemical …, 2017 - ACS Publications
This review classifies and summarizes the past 10–15 years of advancements in the field of
metal-involving (ie, metal-mediated and metal-catalyzed) reactions of oximes. These …

Synthesis, Electronic Structure, and Magnetism of [Ni(6-Mes)2]+: A Two-Coordinate Nickel(I) Complex Stabilized by Bulky N-Heterocyclic Carbenes

RC Poulten, MJ Page, AG Algarra… - Journal of the …, 2013 - ACS Publications
The two-coordinate cationic Ni (I) bis-N-heterocyclic carbene complex [Ni (6-Mes) 2] Br (1)[6-
Mes= 1, 3-bis (2, 4, 6-trimethylphenyl)-3, 4, 5, 6-tetrahydropyrimidin-2-ylidene] has been …

Toward a Magnetostructural Correlation for a Family of Mn6 SMMs

CJ Milios, R Inglis, A Vinslava, R Bagai… - Journal of the …, 2007 - ACS Publications
We have structurally and magnetically characterized a total of 12 complexes based on the
Single-Molecule Magnet (SMM)[MnIII6O2 (sao) 6 (O2CH) 2 (MeOH) 4](1)(where sao2-is the …

An Organometallic Building Block Approach To Produce a Multidecker 4f Single-Molecule Magnet

JJ Le Roy, M Jeletic, SI Gorelsky… - Journal of the …, 2013 - ACS Publications
An organometallic building block strategy was employed to investigate the magnetic
properties of a LnIII organometallic single-ion magnet (SIM) and subsequent single …

Heterometallic [Mn5‐Ln4] Single‐Molecule Magnets with High Anisotropy Barriers

V Mereacre, AM Ako, R Clérac… - … A European Journal, 2008 - Wiley Online Library
The reaction of [Mn6O2 (Piv) 10 (4‐Me‐py) 2.5 (PivH) 1.5](1)(py: pyridine, Piv: pivilate) with
N‐methyldiethanolamine (mdeaH2) and Ln (NO3) 3⋅ 6 H2O in MeCN leads to a series of …

Conversion of a Singlet Silylene to a stable Biradical

KC Mondal, HW Roesky, MC Schwarzer… - Angewandte Chemie …, 2013 - Wiley Online Library
Radicals are probably the most important reactive species in organic chemistry and in
biology.[1] The best known stable triplet biradical is the oxygen molecule, which contains …

Cluster-based single-molecule magnets

CJ Milios, REP Winpenny - Molecular Nanomagnets and Related …, 2015 - Springer
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …

Density functional studies on dinuclear {Ni II Gd III} and trinuclear {Ni II Gd III Ni II} complexes: magnetic exchange and magneto-structural maps

SK Singh, NK Tibrewal, G Rajaraman - Dalton Transactions, 2011 - pubs.rsc.org
Theoretical calculations using density functional methods have been performed on two
dinuclear {NiII–GdIII} and two trinuclear {NiII–GdIII–NiII} complexes having two and three μ …

Coordination clusters of 3d-metals that behave as single-molecule magnets (SMMs): synthetic routes and strategies

D Maniaki, E Pilichos, SP Perlepes - Frontiers in Chemistry, 2018 - frontiersin.org
The area of 3d-metal coordination clusters that behave as Single-Molecule Magnets (SMMs)
is now quite mature within the interdisciplinary field of Molecular Magnetism. This area has …