Noncovalent interactions in proteins and nucleic acids: Beyond hydrogen bonding and π-stacking
Understanding the noncovalent interactions (NCIs) among the residues of proteins and
nucleic acids, and between drugs and proteins/nucleic acids, etc., has extraordinary …
nucleic acids, and between drugs and proteins/nucleic acids, etc., has extraordinary …
Pnictogen bonding in coordination chemistry
The pnictogen bond (PnB) is a noncovalent attraction between electrophilic pnictogen
atoms, originated from the anisotropic distribution of electron density on Pn in a molecular …
atoms, originated from the anisotropic distribution of electron density on Pn in a molecular …
On the importance of σ–hole interactions in crystal structures
A Frontera, A Bauzá - Crystals, 2021 - mdpi.com
Elements from groups 14–18 and periods 3–6 commonly behave as Lewis acids, which are
involved in directional noncovalent interactions (NCI) with electron-rich species (lone pair …
involved in directional noncovalent interactions (NCI) with electron-rich species (lone pair …
Diaryliodoniums as hybrid hydrogen-and halogen-bond-donating organocatalysts for the Groebke–Blackburn–Bienaymé reaction
Dibenziodolium and diphenyliodonium triflates display high catalytic activity for the
multicomponent reaction that leads to a series of imidazopyridines. Density functional theory …
multicomponent reaction that leads to a series of imidazopyridines. Density functional theory …
Sulfonium and selenonium salts as noncovalent organocatalysts for the multicomponent Groebke–Blackburn–Bienaymé reaction
Sulfonium and selenonium salts, represented by S-aryl dibenzothiophenium and Se-aryl
dibenzoselenophenium triflates, were found to exhibit remarkable catalytic activity in the …
dibenzoselenophenium triflates, were found to exhibit remarkable catalytic activity in the …
Activation of a Metal‐Halogen Bond by Halogen Bonding
J Wolf, F Huber, N Erochok, F Heinen… - Angewandte Chemie …, 2020 - Wiley Online Library
In recent years, the non‐covalent interaction of halogen bonding (XB) has found increasing
application in organocatalysis. However, reports of the activation of metal‐ligand bonds by …
application in organocatalysis. However, reports of the activation of metal‐ligand bonds by …
On the importance of pnictogen and chalcogen bonding interactions in supramolecular catalysis
A Frontera, A Bauza - International Journal of Molecular Sciences, 2021 - mdpi.com
In this review, several examples of the application of pnictogen (Pn)(group 15) and
chalcogen (Ch) bonding (group 16) interactions in organocatalytic processes are gathered …
chalcogen (Ch) bonding (group 16) interactions in organocatalytic processes are gathered …
Iodonium salts as efficient iodine (III)-based noncovalent organocatalysts for Knorr-type reactions
SN Yunusova, AS Novikov, NS Soldatova, MA Vovk… - RSC …, 2021 - pubs.rsc.org
Hypervalent iodine (III)-derivatives display higher catalytic activity than other aliphatic and
aromatic iodine (I)–or bromine (I)-containing substrates for a Knorr-type reaction of N-acetyl …
aromatic iodine (I)–or bromine (I)-containing substrates for a Knorr-type reaction of N-acetyl …
Supramolecular Assembly of Metal Complexes by (Aryl)I⋅⋅⋅d [PtII] Halogen Bonds
EA Katlenok, M Haukka, OV Levin… - … A European Journal, 2020 - Wiley Online Library
The theoretical data for the half‐lantern complexes [{Pt ()(μ‐)} 2][1–3; is cyclometalated 2‐Ph‐
benzothiazole; is 2‐SH‐pyridine (1), 2‐SH‐benzoxazole (2), 2‐SH‐tetrafluorobenzothiazole …
benzothiazole; is 2‐SH‐pyridine (1), 2‐SH‐benzoxazole (2), 2‐SH‐tetrafluorobenzothiazole …
Diaryliodonium Tetrachloroplatinates(II): Recognition of a Trifurcated Metal-Involving μ3-I···(Cl,Cl,Pt) Halogen Bond
VV Suslonov, NS Soldatova, DM Ivanov… - Crystal Growth & …, 2021 - ACS Publications
Synthesis and X-ray characterization of the four diaryliodonium tetrachloroplatinates
(II)[Ar1Ar2I] 2 [PtCl4](Ar1/Ar2= Ph/Ph (1), 4-Cl-C6H4/2, 4, 6-(MeO) 3C6H2 (2), 4-Me-C6H4/2 …
(II)[Ar1Ar2I] 2 [PtCl4](Ar1/Ar2= Ph/Ph (1), 4-Cl-C6H4/2, 4, 6-(MeO) 3C6H2 (2), 4-Me-C6H4/2 …