This Review examines recent developments in late transition metal-catalyzed
hydroamination and-amidation reactions. A hydroamination is a reaction in which an N− H …

Hydroaminoalkylation is a powerful, atom-economic catalytic reaction for the reaction of
amines with alkenes and alkynes. This C–H functionalization reaction allows for the atom …

Asymmetric hydroamination allows the direct and selective formation of a new C N bond as
a simple procedure towards valuable scalemic synthons. Huge efforts have recently been …

Using a single half-sandwich iron (II) compound, Cp* Fe (1, 2-Ph2PC6H4S)(NCMe)(Cp*–=
C5Me5–, 1) as a catalyst, reductive coupling of nitroarenes with olefins has been achieved …

The addition of an N–H bond to an olefin is the most direct route for the synthesis of
alkylamines. Currently, intermolecular hydroamination is limited to reactions of a narrow …

Abstract [{N^ N} M (X)(thf) n] alkyl (X= CH (SiMe3) 2) and amide (X= N (SiMe3) 2) complexes
of alkaline earths (M= Ca, Sr, Ba) and divalent rare earths (YbII and EuII) bearing an …

The iridium tetrahydride complex Cp* IrH4 reacts with a range of isobutylaluminum
derivatives of general formula Al (i Bu) x (OAr) 3–x (x= 1, 2) to give the unusual iridium …

A zirconium-catalyzed hydroaminoalkylation of alkynes to access α, β, γ-substituted allylic
amines in an atom-economic fashion is reported. The reaction is compatible with N …

Saturated N-heterocycles are prevalent in pharmaceutical and agrochemical industries, yet
remain challenging to catalytically alkylate. Most strategies for C–H activation of these …

The intermolecular hydroaminoalkylation of unactivated alkenes and vinyl arenes with
secondary amines occurs readily in the presence of tantalum and niobium binaphtholate …