A lysine–cysteine redox switch with an NOS bridge regulates enzyme function

M Wensien, FR von Pappenheim, LM Funk… - Nature, 2021 - nature.com
Disulfide bonds between cysteine residues are important post-translational modifications in
proteins that have critical roles for protein structure and stability, as redox-active catalytic …

Nucleophilic neutralization of organophosphates: lack of selectivity or plenty of versatility?

VB Silva, RB Campos, P Pavez… - The Chemical …, 2021 - Wiley Online Library
Neutralization of organophosphates is an issue of public health and safety, involving
agrochemicals and chemical warfare. A promising approach is the nucleophilic …

Electrochemical functional‐group‐tolerant shono‐type oxidation of cyclic carbamates enabled by aminoxyl mediators

F Wang, M Rafiee, SS Stahl - Angewandte Chemie, 2018 - Wiley Online Library
An electrochemical method has been developed for α‐oxygenations of cyclic carbamates by
using a bicyclic aminoxyl as a mediator and water as the nucleophile. The mediated …

Crown-hydroxylamines are pH-dependent chelating N,O-ligands with a potential for aerobic oxidation catalysis

VK Lesnikov, IS Golovanov, YV Nelyubina… - Nature …, 2023 - nature.com
Despite the rich coordination chemistry, hydroxylamines are rarely used as ligands for
transition metal coordination compounds. This is partially because of the instability of these …

The Formation of 2-Isoxazolines in the Reactions of α, β-Unsaturated Carbonyl Compounds with Hydroxylamine and its Derivatives-A Critical Review

OK Drosik, JW Suwinski - Current Organic Chemistry, 2018 - ingentaconnect.com
Background: For more than one hundred years, it has been known that some 2-isoxazolines
can be experimentally obtained by the addition of hydroxylamine or its derivatives to α, β …

Neuroprotection and lifespan extension in Ppt1−/− mice by NtBuHA: therapeutic implications for INCL

C Sarkar, G Chandra, S Peng, Z Zhang, A Liu… - Nature …, 2013 - nature.com
Infantile neuronal ceroid lipofuscinosis (INCL) is a devastating childhood neurodegenerative
lysosomal storage disease (LSD) that has no effective treatment. It is caused by inactivating …

Energetic Metal–Organic Frameworks Incorporating NH3OH+ for New High-Energy-Density Materials

Y Feng, S Chen, M Deng, T Zhang… - Inorganic Chemistry, 2019 - ACS Publications
Energetic metal–organic frameworks (E-MOFs) have witnessed increasing development
over the past several years. However, as a highly energetic cation, NH3OH+ has never been …

Novel strategy for copper precipitation from cupric complexes wastewater: Catalytic oxidation or reduction self-decomplexation?

Y Gu, Y Sun, W Zheng - Journal of Hazardous Materials, 2023 - Elsevier
Abstract Cupric (Cu (II)) complexes in industrial wastewater are responsible for the failure of
conventional alkaline precipitation, but the properties of cuprous (Cu (I)) complexes at …

Branching cascades: a concise synthetic strategy targeting diverse and complex molecular frameworks

W Liu, V Khedkar, B Baskar, M Schürmann… - Angewandte Chemie …, 2011 - infona.pl
Touch'n'transform: A synthetic strategy based on cascade or domino reaction sequences
enabled the simultaneous incorporation of skeletal diversity and molecular complexity in …

Efficient intramolecular general acid catalysis of nucleophilic attack on a phosphodiester

AJ Kirby, MF Lima, D da Silva… - Journal of the …, 2006 - ACS Publications
The hydrolysis of methyl 8-dimethylamino-1-naphthyl phosphate 4 and its reactions with a
representative range of nucleophiles are catalyzed by the dimethylammonium group at …