Chemistry of meso-Aryl-Substituted Expanded Porphyrins: Aromaticity and Molecular Twist
T Tanaka, A Osuka - Chemical reviews, 2017 - ACS Publications
Since the discovery of its facile synthesis in 2001, meso-aryl-substituted expanded
porphyrins have been developed as a new class of azaannulenes in light of their facile …
porphyrins have been developed as a new class of azaannulenes in light of their facile …
Creation from Confusion and Fusion in the Porphyrin World─ The Last Three Decades of N-Confused Porphyrinoid Chemistry
M Toganoh, H Furuta - Chemical Reviews, 2022 - ACS Publications
Confusion is a novel concept of isomerism in porphyrin chemistry, delivering a steady
stream of new chemistry since the discovery of N-confused porphyrin, a porphyrin mutant, in …
stream of new chemistry since the discovery of N-confused porphyrin, a porphyrin mutant, in …
Electrocatalytic CO2 reduction to alcohols by modulating the molecular geometry and Cu coordination in bicentric copper complexes
Electrocatalytic reduction of CO2 into alcohols of high economic value offers a promising
route to realize resourceful CO2 utilization. In this study, we choose three model bicentric …
route to realize resourceful CO2 utilization. In this study, we choose three model bicentric …
Conjugated porphyrin arrays: synthesis, properties and applications for functional materials
T Tanaka, A Osuka - Chemical Society Reviews, 2015 - pubs.rsc.org
Conjugated porphyrin arrays that possess delocalised electronic networks have, for the most
part, been assembled by using alkene or alkyne type bridging units or by directly connecting …
part, been assembled by using alkene or alkyne type bridging units or by directly connecting …
Expanded porphyrins: intriguing structures, electronic properties, and reactivities
S Saito, A Osuka - Angewandte Chemie International Edition, 2011 - Wiley Online Library
The chemistry of expanded porphyrins, which are higher homologues of porphyrins, has
been intensively explored for the last three decades. Expanded porphyrins exhibit …
been intensively explored for the last three decades. Expanded porphyrins exhibit …
Porphyrinoids, a unique platform for exploring excited-state aromaticity
Recently, Baird (anti) aromaticity has been referred to as a description of excited-state (anti)
aromaticity. With the term of Baird's rule, recent studies have intensively verified that the …
aromaticity. With the term of Baird's rule, recent studies have intensively verified that the …
Synthetic expanded porphyrin chemistry
JL Sessler, D Seidel - Angewandte Chemie International …, 2003 - Wiley Online Library
Expanded porphyrins are synthetic analogues of the porphyrins, and differ from these and
other naturally occurring tetrapyrrolic macrocycles by containing a larger central core with a …
other naturally occurring tetrapyrrolic macrocycles by containing a larger central core with a …
Flexible porphyrinoids
This review underscores the conformational flexibility of porphyrinoids, a unique class of
functional molecules, starting from the smallest triphyrins (1.1. 1) via [18] porphyrins (1.1 …
functional molecules, starting from the smallest triphyrins (1.1. 1) via [18] porphyrins (1.1 …
Figure eights, Möbius bands, and more: conformation and aromaticity of porphyrinoids
M Stępień, N Sprutta… - Angewandte Chemie …, 2011 - Wiley Online Library
The aromatic character of porphyrins, which has significant chemical and biological
consequences, can be substantially altered by judicious modifications of the parent ring …
consequences, can be substantially altered by judicious modifications of the parent ring …
The gauge including magnetically induced current method
H Fliegl, S Taubert, O Lehtonen… - Physical Chemistry …, 2011 - pubs.rsc.org
An overview of applications of the recently developed gauge including magnetically induced
current method (GIMIC) is presented. The GIMIC method is used to obtain magnetically …
current method (GIMIC) is presented. The GIMIC method is used to obtain magnetically …