Advances in synthetic applications of hypervalent iodine compounds

A Yoshimura, VV Zhdankin - Chemical reviews, 2016 - ACS Publications
The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

Electrophilic trifluoromethylation by use of hypervalent iodine reagents

J Charpentier, N Fruh, A Togni - Chemical reviews, 2015 - ACS Publications
1. INTRODUCTION This review article is concerned with the use of compounds 1 and 2
(Figure 1) as effective and very versatile reagents for trifluoromethylation reactions of a …

Figuration of bowl-shaped π-conjugated molecules: properties and functions

M Saito, H Shinokubo, H Sakurai - Materials Chemistry Frontiers, 2018 - pubs.rsc.org
Figuration of bowl-shaped π-conjugated molecules: properties and functions - Materials Chemistry
Frontiers (RSC Publishing) DOI:10.1039/C7QM00593H Royal Society of Chemistry View PDF …

Corannulene: a molecular bowl of carbon with multifaceted properties and diverse applications

E Nestoros, MC Stuparu - Chemical Communications, 2018 - pubs.rsc.org
Unlike typical polycyclic aromatic hydrocarbons, such as coronene, which are flat and
planar, corannulene is a molecular bowl of carbon. It can be imagined as the cap region of …

[HTML][HTML] Recent advances in transition metal-catalyzed Csp2-monofluoro-, difluoro-, perfluoromethylation and trifluoromethylthiolation

G Landelle, A Panossian, S Pazenok… - Beilstein journal of …, 2013 - beilstein-journals.org
In the last few years, transition metal-mediated reactions have joined the toolbox of chemists
working in the field of fluorination for Life-Science oriented research. The successful …

Organocatalytic Asymmetric [3 + 2] Cycloaddition of N-2,2,2-Trifluoroethylisatin Ketimines with β-Trifluoromethyl Electron-Deficient Alkenes: Access to Vicinally Bis …

Y You, WY Lu, ZH Wang, YZ Chen, XY Xu… - Organic …, 2018 - ACS Publications
N-2, 2, 2-Trifluoroethylisatin ketimines with β-trifluoromethyl enones, 3-trifluoroethylidene
oxindole, and 3-trifluoroethylidene benzofuranone can undergo asymmetric [3+ 2] …

Charge carrier mobility in organic molecular materials probed by electromagnetic waves

S Seki, A Saeki, T Sakurai, D Sakamaki - Physical Chemistry Chemical …, 2014 - pubs.rsc.org
Charge carrier mobility is an essential parameter providing control over the performance of
semiconductor devices fabricated using a variety of organic molecular materials. Recent …

Copper-mediated radical 1, 2-bis (trifluoromethylation) of alkenes with sodium trifluoromethanesulfinate

B Yang, XH Xu, FL Qing - Organic letters, 2015 - ACS Publications
An efficient chemoselective 1, 2-bis (trifluoromethylation) of alkenes with CF3SO2Na
promoted by t-BuOOH/CuCl was developed. This protocol provided the first convenient …

Rational Functionalization of a C70 Buckybowl To Enable a C70:Buckybowl Cocrystal for Organic Semiconductor Applications

G Gao, M Chen, J Roberts, M Feng… - Journal of the …, 2020 - ACS Publications
Fullerene fragments, referred to as buckybowls, are garnering interest due to their distinctive
molecular shapes and optoelectronic properties. Here, we report the synthesis and …

Buckybowls: Corannulene and its derivatives

X Li, F Kang, M Inagaki - Small, 2016 - Wiley Online Library
Corannulene, a kind of bowl like polycyclic aromatic hydrocarbon (PAH), whose molecule is
composed of a central pentagon and five closely adjacent hexagons on the pentagon's five …