Iodine capture in porous organic polymers and metal–organic frameworks materials
The enrichment of radioactive iodine in the waste of nuclear industries threatens human
health, and thus the efficient capture of iodine has attracted a great deal of attention in recent …
health, and thus the efficient capture of iodine has attracted a great deal of attention in recent …
Oxygen activation and radical transformations in heme proteins and metalloporphyrins
As a result of the adaptation of life to an aerobic environment, nature has evolved a panoply
of metalloproteins for oxidative metabolism and protection against reactive oxygen species …
of metalloproteins for oxidative metabolism and protection against reactive oxygen species …
[HTML][HTML] Modern quantum chemistry with [Open] Molcas
MOLCAS/OpenMolcas is an ab initio electronic structure program providing a large set of
computational methods from Hartree–Fock and density functional theory to various …
computational methods from Hartree–Fock and density functional theory to various …
Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers
As an alternative technology to energy intensive distillations, adsorptive separation by
porous solids offers lower energy cost and higher efficiency. Herein we report a topology …
porous solids offers lower energy cost and higher efficiency. Herein we report a topology …
Capture, storage, and release of oxygen by metal–organic frameworks (MOFs)
Oxygen is a critical gas for medical and industrial settings. Much of today's global oxygen
supply is via inefficient technologies such as cryogenic distillation, membranes or zeolites …
supply is via inefficient technologies such as cryogenic distillation, membranes or zeolites …
Biomimetic reactivity of oxygen-derived manganese and iron porphyrinoid complexes
Heme proteins utilize the heme cofactor, an iron porphyrin, to perform a diverse range of
reactions including dioxygen binding and transport, electron transfer, and oxidation …
reactions including dioxygen binding and transport, electron transfer, and oxidation …
A base-resistant metalloporphyrin metal–organic framework for C–H bond halogenation
A base-resistant porphyrin metal–organic framework (MOF), namely PCN-602 has been
constructed with 12-connected [Ni8 (OH) 4 (H2O) 2Pz12](Pz= pyrazolate) cluster and a …
constructed with 12-connected [Ni8 (OH) 4 (H2O) 2Pz12](Pz= pyrazolate) cluster and a …
Conceptual and practical aspects of metal–organic frameworks for solid–gas reactions
The presence of site-isolated and well-defined metal sites has enabled the use of metal–
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …
Activation of dioxygen by iron and manganese complexes: a heme and nonheme perspective
S Sahu, DP Goldberg - Journal of the American Chemical Society, 2016 - ACS Publications
The rational design of well-defined, first-row transition metal complexes that can activate
dioxygen has been a challenging goal for the synthetic inorganic chemist. The activation of …
dioxygen has been a challenging goal for the synthetic inorganic chemist. The activation of …
[HTML][HTML] Applications of metal–organic frameworks for green energy and environment: New advances in adsorptive gas separation, storage and removal
The separation of gas molecules with similar physicochemical properties is of high
importance but practically entails a substantial energy penalty in chemical industry …
importance but practically entails a substantial energy penalty in chemical industry …