Following up on scattered reports on interactions of conventional chaotropic ions (for
example, I−, SCN−, ClO4−) with macrocyclic host molecules, biomolecules, and …

The molecular and supramolecular chemistry of atomically precise nanoclusters
encompasses intra-cluster growth, inter-cluster assembly, and cluster-based host-guest …

Aqueous rechargeable Zn batteries (AZBs) are considered to be promising next-generation
battery systems. However, the growth of Zn dendrites and water-induced side reactions have …

Large water-soluble anions with chaotropic character display surprisingly strong
supramolecular interactions in water, for example, with macrocyclic receptors, polymers …

In aqueous solution, low-charged polyoxometalates (POMs) exhibit remarkable self-
assembly properties with nonionic organic matter that have been recently used to develop …

Natural cyclodextrin (CD) macrocycles are known to form diverse inclusion complexes with a
wide variety of organic molecules, but recent work has revealed that inorganic clusters also …

Herein, we show how the chaotropic effect arising from reduced molybdate ions in acidified
aqueous solution is able to amplify drastically weak supramolecular interactions. Time …

Metallacarboranes are a class of inorganic boron clusters that have recently been
recognized as biologically active compounds. Herein, we report on the host–guest …

Perhalogenated closo‐borates represent a new class of membrane carriers. They owe this
activity to their chaotropicity, which enables the transport of hydrophilic molecules across …

The chaotropic character of Keggin-type polyoxotungstate anions was evaluated with
respect to their ability to bind to γ-cyclodextrin (γ-CD) by varying the global charge density of …