Complementary probes for the electrochemical interface

E Pastor, Z Lian, L Xia, D Ecija… - Nature Reviews …, 2024 - nature.com
The functions of electrochemical energy conversion and storage devices rely on the
dynamic junction between a solid and a fluid: the electrochemical interface (EI). Many …

X‐ray imaging for structural evolution and phase transformation dynamics of battery electrodes

MT Shuja, S Thatipamula, MW Khan, M Haris… - Battery …, 2024 - Wiley Online Library
The impending energy crisis entails sustainable battery technologies with improved energy
density, reliability, safety and lifetime. Hence, it is essential to gain detailed insights into the …

Mastering Proton Activities in Aqueous Batteries

L Zhang, C Zhang, EJ Berg - Advanced Materials, 2024 - Wiley Online Library
Advanced aqueous batteries are promising solutions for grid energy storage. Compared
with their organic counterparts, water‐based electrolytes enable fast transport kinetics, high …

Mechanistic Understanding of Additive Reductive Degradation and SEI Formation in High‐Voltage NMC811||SiOx‐Containing Cells via Operando ATR‐FTIR …

M Weiling, C Lechtenfeld, F Pfeiffer… - Advanced Energy …, 2024 - Wiley Online Library
The implementation of silicon (Si)‐containing negative electrodes is widely discussed as an
approach to increase the specific capacity of lithium‐ion batteries. However, challenges …

Operando Photoelectron Spectroscopy Analysis of Li6PS5Cl Electrochemical Decomposition Reactions in Solid-State Batteries

B Aktekin, E Kataev, LM Riegger… - ACS Energy …, 2024 - ACS Publications
It is crucial to understand at which potentials electrolyte decomposition reactions start and
which chemical species are present in the subsequently formed decomposition films, eg …

Unraveling the Role of Solvation and Ion Valency on Redox-Mediated Electrosorption through In Situ Neutron Reflectometry and Ab Initio Molecular Dynamics

R Candeago, H Wang, MT Nguyen, M Doucet… - JACS Au, 2024 - ACS Publications
Solvation and ion valency effects on selectivity of metal oxyanions at redox–polymer
interfaces are explored through in situ spatial-temporally resolved neutron reflectometry …

Tracing the Cross‐Talk Phenomenon of Vinylethylene Carbonate to Unveil its Counterintuitive Influence as an Electrolyte Additive on High‐Voltage Lithium‐Ion …

F Pfeiffer, A Griggio, M Weiling, JF Wang… - Advanced Energy …, 2024 - Wiley Online Library
The formation of effective interphases is crucial to enable high‐performance lithium‐ion
batteries. This can be facilitated by the introduction of electrolyte additives, ensuring …

Electrical Double Layer Formation at Intercalation Cathode–Organic Electrolyte Interfaces During Initial Lithium‐Ion Battery Reactions

J Nakayama, H Zhou, J Izumi… - Advanced Materials …, 2024 - Wiley Online Library
Abstract Information on the cathode/organic–electrolyte interface structure provides clues
regarding the rate and reversibility of lithium intercalation reactions in lithium‐ion batteries …

[HTML][HTML] Operando insights into ammonium-mediated lithium metal stabilization: surface morphology modulation and enhanced SEI development

G Lacarbonara, M Sadd, J Rizell, L Bargnesi… - Journal of Colloid and …, 2024 - Elsevier
Lithium-ion batteries (LiBs) with graphite as an anode and lithiated transition metal oxide as
a cathode are approaching their specific energy and power theoretical values. To overcome …

In Situ Formation of Suspended Graphene Windows for Lab‐Based XPS in Liquid and Gas Environments

ES Jones, C Drivas, JS Gibson, JEN Swallow… - …, 2024 - Wiley Online Library
Environmental cells sealed with photoelectron‐transparent graphene windows are
promising for extending X‐ray photoelectron spectroscopy (XPS) to liquid and high …