Apatites: a new family of catalysts in organic synthesis

M Gruselle - Journal of Organometallic Chemistry, 2015 - Elsevier
The development of green and sustainable chemistry is one of the most exciting challenges
in modern chemistry. In this way, design of new catalysts for heterogeneous processes is of …

Water-mediated structuring of bone apatite

Y Wang, S Von Euw, FM Fernandes, S Cassaignon… - Nature materials, 2013 - nature.com
It is well known that organic molecules from the vertebrate extracellular matrix of calcifying
tissues are essential in structuring the apatite mineral. Here, we show that water also plays a …

Investigation of surface layers on biological and synthetic hydroxyapatites based on bone mineralization process

K Sugimoto, Y Zhou, TGP Galindo, R Kimura… - Biomimetics, 2023 - mdpi.com
In this review, the current status of the influence of added ions (ie, SiO44−, CO32−, etc.) and
surface states (ie, hydrated and non-apatite layers) on the biocompatibility nature of …

The crystallization of amorphous calcium carbonate is kinetically governed by ion impurities and water

M Albéric, L Bertinetti, Z Zou, P Fratzl… - Advanced …, 2018 - Wiley Online Library
Many organisms use amorphous calcium carbonate (ACC) and control its stability by various
additives and water; however, the underlying mechanisms are yet unclear. Here, the effect of …

X-ray photoelectron and ion scattering spectroscopic surface analyses of amorphous and crystalline calcium phosphate nanoparticles with different chemical histories

V Uskoković - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
Abundant hydration, diffusivity, and volatile phase composition render the surface of calcium
phosphates (CPs) a complex dynamic region. Three CP powders were analyzed using X-ray …

Influence of surface acid and base sites on the Guerbet coupling of ethanol to butanol over metal phosphate catalysts

S Hanspal, ZD Young, JT Prillaman, RJ Davis - Journal of catalysis, 2017 - Elsevier
Abstract Hydroxyapatite (HAP; Ca 10 (PO 4) 6 (OH) 2) is a well-recognized catalyst for the
Guerbet coupling of ethanol to butanol. In an effort to explore the role of the anion …

Direct, selective production of aromatic alcohols from ethanol using a tailored bifunctional cobalt–hydroxyapatite catalyst

QN Wang, XF Weng, BC Zhou, SP Lv, S Miao… - ACS …, 2019 - ACS Publications
Aromatic alcohols are essential components of many solvents, coatings, plasticizers, fine
chemicals, and pharmaceuticals. Traditional manufacturing processes involving the …

DRIFTS of probe molecules adsorbed on magnesia, zirconia, and hydroxyapatite catalysts

IM Hill, S Hanspal, ZD Young… - The Journal of Physical …, 2015 - ACS Publications
Acid sites, base sites, and acid–base site pairs on zirconia, magnesia, and hydroxyapatite
were investigated using diffuse reflectance FT-IR spectroscopy (DRIFTS) to evaluate the …

Synthesis modification of hydroxyapatite surface for ethanol conversion: The role of the acidic/basic sites ratio

H Brasil, AFB Bittencourt, KCES Yokoo, PCD Mendes… - Journal of …, 2021 - Elsevier
Several studies have investigated the acidic/basic sites of the hydroxyapatite (HAP) surface.
However, their specific role in the catalytic properties of HAP is still discussed. Here, we …

Fundamentals in adsorption at the solid-gas interface. Concepts and thermodynamics

V Bolis - Calorimetry and thermal methods in catalysis, 2013 - Springer
Some fundamental concepts about the features of a solid material surface and the
adsorption at the gas-solid interface are illustrated. The basic tools dealing with the …