Apatites: a new family of catalysts in organic synthesis
M Gruselle - Journal of Organometallic Chemistry, 2015 - Elsevier
The development of green and sustainable chemistry is one of the most exciting challenges
in modern chemistry. In this way, design of new catalysts for heterogeneous processes is of …
in modern chemistry. In this way, design of new catalysts for heterogeneous processes is of …
Water-mediated structuring of bone apatite
It is well known that organic molecules from the vertebrate extracellular matrix of calcifying
tissues are essential in structuring the apatite mineral. Here, we show that water also plays a …
tissues are essential in structuring the apatite mineral. Here, we show that water also plays a …
Investigation of surface layers on biological and synthetic hydroxyapatites based on bone mineralization process
K Sugimoto, Y Zhou, TGP Galindo, R Kimura… - Biomimetics, 2023 - mdpi.com
In this review, the current status of the influence of added ions (ie, SiO44−, CO32−, etc.) and
surface states (ie, hydrated and non-apatite layers) on the biocompatibility nature of …
surface states (ie, hydrated and non-apatite layers) on the biocompatibility nature of …
The crystallization of amorphous calcium carbonate is kinetically governed by ion impurities and water
Many organisms use amorphous calcium carbonate (ACC) and control its stability by various
additives and water; however, the underlying mechanisms are yet unclear. Here, the effect of …
additives and water; however, the underlying mechanisms are yet unclear. Here, the effect of …
X-ray photoelectron and ion scattering spectroscopic surface analyses of amorphous and crystalline calcium phosphate nanoparticles with different chemical histories
V Uskoković - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
Abundant hydration, diffusivity, and volatile phase composition render the surface of calcium
phosphates (CPs) a complex dynamic region. Three CP powders were analyzed using X-ray …
phosphates (CPs) a complex dynamic region. Three CP powders were analyzed using X-ray …
Influence of surface acid and base sites on the Guerbet coupling of ethanol to butanol over metal phosphate catalysts
Abstract Hydroxyapatite (HAP; Ca 10 (PO 4) 6 (OH) 2) is a well-recognized catalyst for the
Guerbet coupling of ethanol to butanol. In an effort to explore the role of the anion …
Guerbet coupling of ethanol to butanol. In an effort to explore the role of the anion …
Direct, selective production of aromatic alcohols from ethanol using a tailored bifunctional cobalt–hydroxyapatite catalyst
QN Wang, XF Weng, BC Zhou, SP Lv, S Miao… - ACS …, 2019 - ACS Publications
Aromatic alcohols are essential components of many solvents, coatings, plasticizers, fine
chemicals, and pharmaceuticals. Traditional manufacturing processes involving the …
chemicals, and pharmaceuticals. Traditional manufacturing processes involving the …
DRIFTS of probe molecules adsorbed on magnesia, zirconia, and hydroxyapatite catalysts
Acid sites, base sites, and acid–base site pairs on zirconia, magnesia, and hydroxyapatite
were investigated using diffuse reflectance FT-IR spectroscopy (DRIFTS) to evaluate the …
were investigated using diffuse reflectance FT-IR spectroscopy (DRIFTS) to evaluate the …
Synthesis modification of hydroxyapatite surface for ethanol conversion: The role of the acidic/basic sites ratio
Several studies have investigated the acidic/basic sites of the hydroxyapatite (HAP) surface.
However, their specific role in the catalytic properties of HAP is still discussed. Here, we …
However, their specific role in the catalytic properties of HAP is still discussed. Here, we …
Fundamentals in adsorption at the solid-gas interface. Concepts and thermodynamics
V Bolis - Calorimetry and thermal methods in catalysis, 2013 - Springer
Some fundamental concepts about the features of a solid material surface and the
adsorption at the gas-solid interface are illustrated. The basic tools dealing with the …
adsorption at the gas-solid interface are illustrated. The basic tools dealing with the …