Clip chemistry: diverse (bio)(macro) molecular and material function through breaking covalent bonds
In the two decades since the introduction of the “click chemistry” concept, the toolbox of “click
reactions” has continually expanded, enabling chemists, materials scientists, and biologists …
reactions” has continually expanded, enabling chemists, materials scientists, and biologists …
Engineering precise sequence-defined polymers for advanced functions
Unlike natural macromolecules (eg, nucleic acids and proteins) possessing precisely
defined molar mass, chain sequence, chirality, and topology, synthetic polymers are typically …
defined molar mass, chain sequence, chirality, and topology, synthetic polymers are typically …
Sequence-and stereo-defined macromolecules: properties and emerging functionalities
R Szweda - Progress in Polymer Science, 2023 - Elsevier
Natural macromolecules, such as proteins and nucleic acids, display various complex
functionalities in biological systems. These functionalities depend on the macromolecular …
functionalities in biological systems. These functionalities depend on the macromolecular …
Properties and applications of precision oligomer materials; where organic and polymer chemistry join forces
B van Genabeek, BAG Lamers… - Journal of Polymer …, 2021 - Wiley Online Library
Precise oligomeric materials constitute a growing area of research with implications for
various applications as well as fundamental studies. Notably, this field of science which can …
various applications as well as fundamental studies. Notably, this field of science which can …
Combining hydroxyl-yne and thiol-ene click reactions to facilely access sequence-defined macromolecules for high-density data storage
B Song, D Lu, A Qin, BZ Tang - Journal of the American Chemical …, 2021 - ACS Publications
Through mimicking the synthesis of hereditary-information-containing nucleic acids,
scientists are committed to synthesizing sequence-defined macromolecules. Herein, a …
scientists are committed to synthesizing sequence-defined macromolecules. Herein, a …
Discrete block copolymers with diverse architectures: resolving complex spherical phases with one monomer resolution
This work describes the first rigorous example of a single-component block copolymer
system forming unconventional spherical phases. A library of discrete block polymers with …
system forming unconventional spherical phases. A library of discrete block polymers with …
The role of architectural engineering in macromolecular self-assemblies via non-covalent interactions: A molecular LEGO approach
Macromolecular self-assembly has made explosive development in the last several
decades, are being extensively explored in the fields of drug delivery, lithography, catalysis …
decades, are being extensively explored in the fields of drug delivery, lithography, catalysis …
Controlled Self‐Assembly of Discrete Amphiphilic Oligourethanes with a Cascade Self‐Immolative Motif
Discrete polymers offer an excellent platform for comprehending the interplay between
precise chain structures, distinctive self‐assembly behavior, and functional applications …
precise chain structures, distinctive self‐assembly behavior, and functional applications …
Binary tree-inspired digital dendrimer
Z Huang, Q Shi, J Guo, F Meng, Y Zhang, Y Lu… - Nature …, 2019 - nature.com
Digital polymers with precisely ordered units acting as the coded 0-or 1-bit, are introduced
as a promising option for molecular data storage. However, the pursuit of better performance …
as a promising option for molecular data storage. However, the pursuit of better performance …
[HTML][HTML] The current science of sequence-defined macromolecules
A fundamental endeavour in macromolecular science is the control of molecular-level
complexity, including molecular weight distribution, end groups and architecture. Since the …
complexity, including molecular weight distribution, end groups and architecture. Since the …