Organic peroxides in aerosol: key reactive intermediates for multiphase processes in the atmosphere

S Wang, Y Zhao, AWH Chan, M Yao, Z Chen… - Chemical …, 2023 - ACS Publications
Organic peroxides (POs) are organic molecules with one or more peroxide (− O–O−)
functional groups. POs are commonly regarded as chemically labile termination products …

Evaluating organic aerosol sources and evolution with a combined molecular composition and volatility framework using the filter inlet for gases and aerosols …

JA Thornton, C Mohr, S Schobesberger… - Accounts of Chemical …, 2020 - ACS Publications
Conspectus The complex array of sources and transformations of organic carbonaceous
material that comprises an important fraction of atmospheric fine particle mass, known as …

[HTML][HTML] An extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF) for online measurement of atmospheric aerosol particles

FD Lopez-Hilfiker, V Pospisilova… - Atmospheric …, 2019 - amt.copernicus.org
Real-time, online measurements of atmospheric organic aerosol (OA) composition are an
essential tool for determining the emissions sources and physicochemical processes …

Molecular understanding of the enhancement in organic aerosol mass at high relative humidity

M Surdu, H Lamkaddam, DS Wang… - Environmental …, 2023 - ACS Publications
The mechanistic pathway by which high relative humidity (RH) affects gas–particle
partitioning remains poorly understood, although many studies report increased secondary …

Marine biogenic emissions of benzene and toluene and their contribution to secondary organic aerosols over the polar oceans

C Wohl, Q Li, CA Cuevas, RP Fernandez, M Yang… - Science …, 2023 - science.org
Reactive trace gas emissions from the polar oceans are poorly characterized, even though
their effects on atmospheric chemistry and aerosol formation are crucial for assessing …

Time-Resolved Molecular Characterization of Secondary Organic Aerosol Formed from OH and NO3 Radical Initiated Oxidation of a Mixture of Aromatic Precursors

V Kumar, JG Slowik, U Baltensperger… - Environmental …, 2023 - ACS Publications
Aromatic hydrocarbons (ArHCs) and oxygenated aromatic hydrocarbons (ArHC–OHs) are
emitted from a variety of anthropogenic activities and are important precursors of secondary …

Superoxide formation from aqueous reactions of biogenic secondary organic aerosols

J Wei, T Fang, C Wong, PSJ Lakey… - Environmental …, 2020 - ACS Publications
Reactive oxygen species (ROS) play a central role in aqueous-phase processing and health
effects of atmospheric aerosols. Although hydroxyl radical (• OH) and hydrogen peroxide …

Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases

Y Zhang, R Liu, D Yang, Y Guo, M Li, K Hou - TrAC Trends in Analytical …, 2023 - Elsevier
Chemical ionization mass spectrometry (CIMS) is a powerful tool for on-line characterization
of atmospheric trace species and reveal of new atmospheric oxidation mechanisms. The …

Unexpectedly efficient aging of organic aerosols mediated by autoxidation

W Zhang, Z Zhao, C Shen, H Zhang - Environmental Science & …, 2023 - ACS Publications
Multiphase oxidative aging is a ubiquitous process for atmospheric organic aerosols (OA).
But its kinetics was often found to be slow in previous laboratory studies where high hydroxyl …

A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from -pinene ozonolysis

J Zhao, E Häkkinen, F Graeffe… - Atmospheric …, 2023 - acp.copernicus.org
Highly oxygenated organic molecules (HOMs) are important for the formation of secondary
organic aerosol (SOA), which poses serious health risks and exerts great influence on …