[HTML][HTML] Radical-promoted single-unit monomer insertion (SUMI)[aka. reversible-deactivation radical addition (RDRA)]
We survey progress in the development of the processes for radical-promoted single-unit
monomer insertion (SUMI) or reversible deactivation radical addition (RDRA), focussing on …
monomer insertion (SUMI) or reversible deactivation radical addition (RDRA), focussing on …
RAFT polymerization of vinyl esters: synthesis and applications
This article is the first comprehensive review on the study and use of vinyl ester monomers in
reversible addition fragmentation chain transfer (RAFT) polymerization. It covers all the …
reversible addition fragmentation chain transfer (RAFT) polymerization. It covers all the …
Living radical polymerization by the RAFT process–a second update
This paper provides a second update to the review of reversible deactivation radical
polymerization achieved with thiocarbonylthio compounds (ZC (= S) SR) by a mechanism of …
polymerization achieved with thiocarbonylthio compounds (ZC (= S) SR) by a mechanism of …
Amphiphilic Poly(vinyl acetate)-b-poly(N-vinylpyrrolidone) and Novel Double Hydrophilic Poly(vinyl alcohol)-b-poly(N-vinylpyrrolidone) Block Copolymers …
A Debuigne, N Willet, R Jérôme… - Macromolecules, 2007 - ACS Publications
Well-defined amphiphilic block copolymers of poly (vinyl acetate)(PVAc) and poly (N-
vinylpyrrolidone)(PN VP) were synthesized by cobalt-mediated radical polymerization …
vinylpyrrolidone)(PN VP) were synthesized by cobalt-mediated radical polymerization …
Innovative NMR Strategies for Complex Macromolecules
In recent years there has been an increasing research emphasis on complex
macromolecular systems. These include polymers with precise control of structures …
macromolecular systems. These include polymers with precise control of structures …
Macromolecular design by interchange of xanthates: background, design, scope and applications
D Taton, M Destarac, SZ Zard - Handbook of RAFT …, 2008 - Wiley Online Library
Free-radical polymerization is extensively utilized industrially, with about 50% of polymeric
materials being produced by this chain process [1]. Compared to ionic polymerizations, free …
materials being produced by this chain process [1]. Compared to ionic polymerizations, free …
Universal xanthate‐mediated controlled free radical polymerizations of the “less activated” vinyl monomers
The living free radical polymerizations of three “less activated” monomers (LAMs), vinyl
acetate, N‐vinylcarbazole, and N‐vinylpyrrolidone, were successfully achieved in the …
acetate, N‐vinylcarbazole, and N‐vinylpyrrolidone, were successfully achieved in the …
Molecular weight and tacticity of oligoacrylates by capillary electrophoresis–mass spectrometry
Oligo (acrylic acid) efficiently stabilizes polymeric particles, especially particles produced by
reversible addition–fragmentation chain transfer (RAFT)(as hydrophilic block of an …
reversible addition–fragmentation chain transfer (RAFT)(as hydrophilic block of an …
Radical addition-fragmentation chemistry and RAFT polymerization
This chapter traces the development of addition-fragmentation chain transfer agents and
related ring-opening monomers highlighting recent innovation in these areas. The major …
related ring-opening monomers highlighting recent innovation in these areas. The major …
Reversible Deactivation Radical Polymerization: RAFT
G Moad - … Engineering: From Precise Synthesis to Macroscopic …, 2022 - Wiley Online Library
RAFT polymerization is a form of reversible deactivation radical polymerization (RDRP),
which with appropriate attention to reagents and reaction conditions can possess the …
which with appropriate attention to reagents and reaction conditions can possess the …