Concepts relevant for the kinetic analysis of reversible reaction systems

NK Razdan, TC Lin, A Bhan - Chemical Reviews, 2023 - ACS Publications
The net rate of a reversible chemical reaction is the difference between unidirectional rates
of traversal along forward and reverse reaction paths. In a multistep reaction sequence, the …

Critical literature review of the kinetics for the oxidative dehydrogenation of propane over well-defined supported vanadium oxide catalysts

CA Carrero, R Schlögl, IE Wachs, R Schomaecker - ACS catalysis, 2014 - ACS Publications
Producing propene by the oxidative dehydrogenation of propane (ODH) has become an
attractive and feasible route for bridging the propene production-demand gap, either as a …

Kinetics of Oxidative Dehydrogenation of C2‐C3 Alkanes on Oxide Catalysts

R Grabowski - Catalysis Reviews, 2006 - Taylor & Francis
This review is a survey of the main facts and concepts appeared in the last years on kinetics
of oxidative dehydrogenation (ODH) of ethane, propane, butane and isobutane. The accent …

Isotopic tracer and kinetic studies of oxidative dehydrogenation pathways on vanadium oxide catalysts

K Chen, A Khodakov, J Yang, AT Bell, E Iglesia - Journal of Catalysis, 1999 - Elsevier
Kinetic analysis and isotopic tracer studies were used to identify elementary steps and their
reversibility in the oxidative dehydrogenation of propane on VOx/ZrO2 catalysts with VOx …

Ni–Nb–O mixed oxides as highly active and selective catalysts for ethene production via ethane oxidative dehydrogenation. Part II: Mechanistic aspects and kinetic …

E Heracleous, AA Lemonidou - Journal of Catalysis, 2006 - Elsevier
In this work, transient and SSITKA experiments with isotopic 18O2 were conducted to study
the nature of oxygen species participating in the reaction of ethane oxidative …

Kinetic isotopic effects in oxidative dehydrogenation of propane on vanadium oxide catalysts

K Chen, E Iglesia, AT Bell - Journal of Catalysis, 2000 - Elsevier
Kinetic isotopic effects (KIEs) for oxidative dehydrogenation of propane were measured on
10 wt% V2O5/ZrO2. Normal KIEs were obtained using CH3CH2CH3 and CD3CD2CD3 as …

Influence of tight confinement on selective oxidative dehydrogenation of ethane on MoVTeNb mixed oxides

L Annamalai, Y Liu, S Ezenwa, Y Dang, SL Suib… - ACS …, 2018 - ACS Publications
M1 phase MoVTeNb mixed oxides exhibit unique catalytic properties that lead to high C2H4
yields in oxidative conversion of C2H6 at moderate temperatures. The role of the heptagonal …

Microwave-activated structured reactors to maximize propylene selectivity in the oxidative dehydrogenation of propane

A Ramirez, JL Hueso, R Mallada… - Chemical Engineering …, 2020 - Elsevier
Microwave (MW) heating has been applied to increase the selectivity to propylene in the
oxidative dehydrogenation (ODH) of propane. The preferential heating of the solid monolith …

Oxidative dehydrogenation of propane on V2O5/Al2O3 and V2O5/TiO2 catalysts: understanding the effect of support by parameter estimation

K Routray, K Reddy, G Deo - Applied Catalysis A: General, 2004 - Elsevier
In this paper, the effect of the oxide support for supporting the vanadium oxide phase is
studied by estimating the reaction parameters for the oxidative dehydrogenation of propane …

The selective oxidative activation of light alkanes. From supported vanadia to multicomponent bulk V-containing catalysts

JML Nieto - Topics in Catalysis, 2006 - Springer
V-containing materials have been proposed as active and selective catalysts in the selective
oxidative transformation of C 2–C 4 alkanes to the corresponding olefins, oxygenates and …