Concepts relevant for the kinetic analysis of reversible reaction systems
The net rate of a reversible chemical reaction is the difference between unidirectional rates
of traversal along forward and reverse reaction paths. In a multistep reaction sequence, the …
of traversal along forward and reverse reaction paths. In a multistep reaction sequence, the …
Critical literature review of the kinetics for the oxidative dehydrogenation of propane over well-defined supported vanadium oxide catalysts
Producing propene by the oxidative dehydrogenation of propane (ODH) has become an
attractive and feasible route for bridging the propene production-demand gap, either as a …
attractive and feasible route for bridging the propene production-demand gap, either as a …
Kinetics of Oxidative Dehydrogenation of C2‐C3 Alkanes on Oxide Catalysts
R Grabowski - Catalysis Reviews, 2006 - Taylor & Francis
This review is a survey of the main facts and concepts appeared in the last years on kinetics
of oxidative dehydrogenation (ODH) of ethane, propane, butane and isobutane. The accent …
of oxidative dehydrogenation (ODH) of ethane, propane, butane and isobutane. The accent …
Isotopic tracer and kinetic studies of oxidative dehydrogenation pathways on vanadium oxide catalysts
Kinetic analysis and isotopic tracer studies were used to identify elementary steps and their
reversibility in the oxidative dehydrogenation of propane on VOx/ZrO2 catalysts with VOx …
reversibility in the oxidative dehydrogenation of propane on VOx/ZrO2 catalysts with VOx …
Ni–Nb–O mixed oxides as highly active and selective catalysts for ethene production via ethane oxidative dehydrogenation. Part II: Mechanistic aspects and kinetic …
E Heracleous, AA Lemonidou - Journal of Catalysis, 2006 - Elsevier
In this work, transient and SSITKA experiments with isotopic 18O2 were conducted to study
the nature of oxygen species participating in the reaction of ethane oxidative …
the nature of oxygen species participating in the reaction of ethane oxidative …
Kinetic isotopic effects in oxidative dehydrogenation of propane on vanadium oxide catalysts
Kinetic isotopic effects (KIEs) for oxidative dehydrogenation of propane were measured on
10 wt% V2O5/ZrO2. Normal KIEs were obtained using CH3CH2CH3 and CD3CD2CD3 as …
10 wt% V2O5/ZrO2. Normal KIEs were obtained using CH3CH2CH3 and CD3CD2CD3 as …
Influence of tight confinement on selective oxidative dehydrogenation of ethane on MoVTeNb mixed oxides
M1 phase MoVTeNb mixed oxides exhibit unique catalytic properties that lead to high C2H4
yields in oxidative conversion of C2H6 at moderate temperatures. The role of the heptagonal …
yields in oxidative conversion of C2H6 at moderate temperatures. The role of the heptagonal …
Microwave-activated structured reactors to maximize propylene selectivity in the oxidative dehydrogenation of propane
Microwave (MW) heating has been applied to increase the selectivity to propylene in the
oxidative dehydrogenation (ODH) of propane. The preferential heating of the solid monolith …
oxidative dehydrogenation (ODH) of propane. The preferential heating of the solid monolith …
Oxidative dehydrogenation of propane on V2O5/Al2O3 and V2O5/TiO2 catalysts: understanding the effect of support by parameter estimation
In this paper, the effect of the oxide support for supporting the vanadium oxide phase is
studied by estimating the reaction parameters for the oxidative dehydrogenation of propane …
studied by estimating the reaction parameters for the oxidative dehydrogenation of propane …
The selective oxidative activation of light alkanes. From supported vanadia to multicomponent bulk V-containing catalysts
JML Nieto - Topics in Catalysis, 2006 - Springer
V-containing materials have been proposed as active and selective catalysts in the selective
oxidative transformation of C 2–C 4 alkanes to the corresponding olefins, oxygenates and …
oxidative transformation of C 2–C 4 alkanes to the corresponding olefins, oxygenates and …