Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …
and selectivity. However, the structural complexity and vulnerability hamper the application …
First-row transition metal-based materials derived from bimetallic metal–organic frameworks as highly efficient electrocatalysts for electrochemical water splitting
Electrochemical water splitting is a mature technology for hydrogen generation. Numerous
studies have focused on the development of highly efficient electrocatalysts to produce …
studies have focused on the development of highly efficient electrocatalysts to produce …
MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
Two-dimensional polymers and polymerizations
Synthetic chemists have developed robust methods to synthesize discrete molecules, linear
and branched polymers, and disordered cross-linked networks. However, two-dimensional …
and branched polymers, and disordered cross-linked networks. However, two-dimensional …
MOF-based membranes for gas separations
Metal–organic frameworks (MOFs) represent the largest known class of porous crystalline
materials ever synthesized. Their narrow pore windows and nearly unlimited structural and …
materials ever synthesized. Their narrow pore windows and nearly unlimited structural and …
Understanding and controlling the nucleation and growth of metal–organic frameworks
Metal–organic frameworks offer a diverse landscape of building blocks to design high
performance materials for implications in almost every major industry. With this diversity …
performance materials for implications in almost every major industry. With this diversity …
Metal–organic framework-based catalysts with single metal sites
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
Destruction of metal–organic frameworks: positive and negative aspects of stability and lability
Metal–organic frameworks (MOFs), constructed from organic linkers and inorganic building
blocks, are well-known for their high crystallinity, high surface areas, and high component …
blocks, are well-known for their high crystallinity, high surface areas, and high component …
25 years of reticular chemistry
At its core, reticular chemistry has translated the precision and expertise of organic and
inorganic synthesis to the solid state. While initial excitement over metal–organic …
inorganic synthesis to the solid state. While initial excitement over metal–organic …
Self-sacrifice MOFs for heterogeneous catalysis: Synthesis mechanisms and future perspectives
This review depicts the exposure of self-sacrifice MOF, their structure, synthesis as well as
potential application from a prodigious angle. We elaborated critically each of the self …
potential application from a prodigious angle. We elaborated critically each of the self …