Chemistry on a half‐shell: synthesis and derivatization of buckybowls

A Sygula - European Journal of Organic Chemistry, 2011 - Wiley Online Library
Buckybowls, bowl‐shaped polycyclic aromatic hydrocarbons structurally related to
fullerenes, represent a class of hydrocarbons with unique properties and a potential for …

Buckybowls: Corannulene and its derivatives

X Li, F Kang, M Inagaki - Small, 2016 - Wiley Online Library
Corannulene, a kind of bowl like polycyclic aromatic hydrocarbon (PAH), whose molecule is
composed of a central pentagon and five closely adjacent hexagons on the pentagon's five …

Synthesis, structures, and physical properties of aromatic molecular-bowl hydrocarbons

YT Wu, JS Siegel - Polyarenes I, 2014 - Springer
This chapter summarizes the synthesis, physical properties, structure, and crystal packing of
buckybowls. Buckybowls exemplify an intermediate class of polynuclear aromatic …

Flat corannulene: when a transition state becomes a stable molecule

E Solel, D Pappo, O Reany, T Mejuch… - Chemical …, 2020 - pubs.rsc.org
Flat corannulene has been considered so far only as a transition state of the bowl-to-bowl
inversion process. This study was driven by the prediction that substituents with strong steric …

Ullmann Reactions of Carbon Nanotubes—Advantageous and Unexplored Functionalization toward Tunable Surface Chemistry

A Kolanowska, AW Kuziel, RG Jędrysiak, M Krzywiecki… - Nanomaterials, 2019 - mdpi.com
We demonstrate Ullmann-type reactions as novel and advantageous functionalization of
carbon nanotubes (CNTs) toward tunable surface chemistry. The functionalization routes …

Deca-heterosubstituted corannulenes

A Pogoreltsev, E Solel, D Pappo… - Chemical …, 2012 - pubs.rsc.org
The Cu (I)-catalyzed Ullmann condensation reaction between aliphatic alcohols and sym-
pentachlorocorannulene provides a convenient entry to 1, 3, 5, 7, 9 …

Synthesis of indacenopicene derivatives

J Bayer - 2022 - kops.uni-konstanz.de
The research field of sp2-hybridized structures has fascinated researches in the fields of
chemistry, physics and material science for a very long time starting in 1825 with Michael …

Acid-catalyzed synthesis of condensed polycyclic diaryl ethers from arenols

S Tanii, M Arisawa, M Yamaguchi - Chemical Communications, 2019 - pubs.rsc.org
Diaryl ethers containing condensed polycyclic aryl groups were synthesized from arenols in
the presence of a catalytic amount of p-chlorobenzenesulfonic acid. Symmetrical binaphthyl …

Ullmann Condensation Today: Arylation of Alcohols and Thiols with Aryl Halides

A Tlili, M Taillefer - Copper‐Mediated Cross‐Coupling …, 2013 - Wiley Online Library
This chapter surveys C (aryl)—O and C (aryl)—S bond‐forming reactions via copper‐
catalyzed couplings of oxygen (water, alcohols, phenols) and sulfur (thiols, thiophenols) …

A Density Functional Theory Investigation of Intramolecular Dispersion Forces in Buckyball-Buckybowl Complexes

I Welsh - 2013 - openaccess.wgtn.ac.nz
The electron-rich, concave face of corannulene makes it an ideal candidate to host electron-
deficient fullerenes, such as C60. The host–guest system is dominated by weak van …