Chemo-and stereoselective CH oxidations and epoxidations/cis-dihydroxylations with H2O2, catalyzed by non-heme iron and manganese complexes

EP Talsi, KP Bryliakov - Coordination Chemistry Reviews, 2012 - Elsevier
The discovery of simple and efficient catalyst systems for the selective oxofunctionalization
of hydrocarbons is a challenging task of modern chemistry. The biomimetic approach, which …

New trends in oxidative functionalization of carbon–hydrogen bonds: A review

GB Shul'pin - Catalysts, 2016 - mdpi.com
This review describes new reactions catalyzed by recently discovered types of metal
complexes and catalytic systems (catalyst+ co-catalyst). Works of recent years (mainly 2010 …

Efficient stereo-and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate

K Kamata, K Yonehara, Y Nakagawa, K Uehara… - Nature …, 2010 - nature.com
Direct functionalization of alkanes by oxidation of C–H bonds to form alcohols under mild
conditions is a challenge for synthetic chemistry. Most alkanes contain a large number of C …

Multicopper complexes and coordination polymers for mild oxidative functionalization of alkanes

AM Kirillov, MV Kirillova, AJL Pombeiro - Coordination Chemistry Reviews, 2012 - Elsevier
Alkanes (main components of natural gas and oil) are rather inert compounds and their
functionalization under mild conditions, toward the synthesis of added value organic …

C–H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity

GB Shul'pin - Dalton Transactions, 2013 - pubs.rsc.org
This brief essay consists of a few “exciting stories” devoted to relations within a metal-
complex catalyst between a metal ion and a coordinated ligand. When, as in the case of a …

Pyrazinecarboxylic acid and analogs: Highly efficient co-catalysts in the metal-complex-catalyzed oxidation of organic compounds

AM Kirillov, GB Shul'pin - Coordination Chemistry Reviews, 2013 - Elsevier
The development of new metal complex catalysts and efficient protocols for the mild and
selective oxidation of alkanes, arenes, olefins, alcohols, and other organic substrates is a …

Mechanism of oxidations with H2O2 catalyzed by vanadate anion or oxovanadium (V) triethanolaminate (vanadatrane) in combination with pyrazine-2-carboxylic acid …

MV Kirillova, ML Kuznetsov, VB Romakh… - Journal of …, 2009 - Elsevier
The oxovanadium (V) triethanolaminate complex (vanadatrane, 2), in the presence of
pyrazine-2-carboxylic acid (PCA) and H2O2, is shown to act as a catalyst for the efficient …

Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with H2O2, Catalyzed by Aminopyridine Manganese Complexes

RV Ottenbacher, DG Samsonenko, EP Talsi… - Organic …, 2012 - ACS Publications
Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with
H2O2, Catalyzed by Aminopyridine Manganese Complexes | Organic Letters ACS ACS …

Preparation and characterization of mesoporous silica supported cobalt oxide as a catalyst for the oxidation of cyclohexanol

J Taghavimoghaddam, GP Knowles… - Journal of Molecular …, 2012 - Elsevier
Cobalt oxide catalysts supported on mesoporous silica SBA-15 were prepared by the “two-
solvent” method and compared with analogous catalysts prepared by the more conventional …

Oxidation of alkanes and alcohols with hydrogen peroxide catalyzed by complex Os3(CO)10(µ‐H)2

GB Shul'pin, YN Kozlov, LS Shul'pina… - Applied …, 2010 - Wiley Online Library
Trinuclear carbonyl hydride cluster, Os3 (CO) 10 (µ‐H) 2, catalyzes oxidation of cyclooctane
to cyclooctyl hydroperoxide by hydrogen peroxide in acetonitrile solution. The …