Crystal chemistry of the monazite structure

N Clavier, R Podor, N Dacheux - Journal of the European Ceramic Society, 2011 - Elsevier
The AXO4 monazite-type compounds form an extended family that is described in this
review in terms of field of stability versus composition. All the substitution possibilities on the …

Crystalline phosphates for HLW immobilization-composition, structure, properties and production of ceramics. Spark Plasma Sintering as a promising sintering …

AI Orlova - Journal of Nuclear Materials, 2022 - Elsevier
Available publications on crystalline materials used to immobilize HLW and actinides have
been analyzed. Select compounds and solid solutions covered in this paper are phosphates …

Aqueous stability of thorium and rare earth metals in monazite hydrometallurgy: Eh–pH diagrams for the systems Th–, Ce–, La–, Nd–(PO4)–(SO4)–H2O at 25 C

E Kim, K Osseo-Asare - Hydrometallurgy, 2012 - Elsevier
Potential vs. pH or Eh–pH diagrams for the systems Th–, La–, Nd–, Ce–,(PO4)–(SO4)–H2O
at 25° C were generated using the HSC5. 0 software. The thermodynamic data available in …

Monazite as a suitable actinide waste form

H Schlenz, J Heuser, A Neumann, S Schmitz… - 2013 - degruyter.com
The conditioning of radioactive waste from nuclear power plants and in some countries even
of weapons plutonium is an important issue for science and society. Therefore the research …

Monoclinic Form of the Rhabdophane Compounds: REEPO4·0.667H2O

A Mesbah, N Clavier, E Elkaim, C Gausse… - Crystal growth & …, 2014 - ACS Publications
Hydrated rhabdophane with a general formula REEPO4· n H2O (REE: La→ Dy) has been
always considered to crystallize in the hexagonal system. A recent re-examination of this …

New insights into phosphate based materials for the immobilisation of actinides

S Neumeier, Y Arinicheva, Y Ji, JM Heuser… - Radiochimica …, 2017 - degruyter.com
This paper focuses on major phosphate-based ceramic materials relevant for the
immobilisation of Pu, minor actinides, fission and activation products. Key points addressed …

Optimized thermodynamic properties of REE aqueous species (REE3+ and REEOH2+) and experimental database for modeling the solubility of REE phosphate …

R Pan, AP Gysi, GD Miron, C Zhu - Chemical Geology, 2024 - Elsevier
Rare earth elements (REE) are critical elements found in monazite, xenotime, and hydrated
REE phosphates which typically form in hydrothermal mineral deposits. Accurate predictions …

Determination of the Solubility of Rhabdophanes LnPO4·0.667H2O (Ln = La to Dy)

C Gausse, S Szenknect, DW Qin… - European Journal of …, 2016 - Wiley Online Library
A systematic study of the solubility of the rhabdophanes LnPO4· 0.667 H2O (Ln= La–Dy)
was performed through oversaturation and undersaturation experiments at different …

Incorporation of Th4+ and Sr2+ into Rhabdophane/Monazite by Wet Chemistry: Structure and Phase Stability

X Zhao, W Wang, Y Teng, Y Li, X Ma, Y Liu… - Inorganic …, 2023 - ACS Publications
Rhabdophane is an important permeable reactive barrier to enrich radionuclides from
groundwater and has been envisaged to host radionuclides in the backend of the nuclear …

Energetics of hydroxylbastnäsite solid solutions, La1− xNdxCO3OH

VG Goncharov, H Nisbet, A Strzelecki… - … et Cosmochimica Acta, 2022 - Elsevier
Bastnäsites (LnCO 3 (F, OH)) are a group of common rare earth elements (REE)-bearing
minerals and are one of the primary global sources of REE. Due to the chemical similarities …