Berzelius stated that catalysts remain unaltered in their reaction environment. However,
catalyst deactivation always becomes noticeable at certain timescales, frequently hindering …

Deactivation leads to loss of catalyst activity or selectivity with increasing reaction time, but
has attracted less academic attention in homogeneous catalysis than is justified by its …

In situ catalysis studies seek insight into species present under reaction conditions to
elucidate reaction mechanisms and understand the atomistic details of the active catalyst …

Ethylene oligomerization to produce 1-alkenes is a cornerstone of organometallic research.
The original α-olefin commercial catalyst system, triethylaluminum, has grown to become …

In this perspective, the HERFD-XANES (high energy resolution fluorescence detected X-ray
absorption near edge structure) and Kβ2, 5-or V2C-XES (valence-to-core X-ray emission …

The objective of this review is the analysis and comment of recent publication results (from
July 2010 until February 2017) obtained for selective ethylene oligomerization toward 1 …

With greater market demand, interest in the selective production of linear α-olefins has been
increasing. This review discusses the principles underlying the evolution of the ligand …

Observing and understanding the phenomena associated with the reaction mechanisms
and catalyst deactivation in molecular catalysis is a very challenging task in green chemistry …

Design tactics and mechanistic studies both remain as fundamental challenges during the
exploitations of earth-abundant molecular electrocatalysts for CO2 reduction, especially for …

In this review we provide an overview of the potential of synchrotron radiation techniques to
understand the structural and electronic properties of coordination compounds. Besides the …