Hydrogen spillover. Facts and fiction

R Prins - Chemical reviews, 2012 - ACS Publications
1. INTRODUCTION In 1964, Khoobiar reported that WO3 is reduced by H2 to blue WO3− x
when it is in contact with a Pt catalyst. 1 The blue color appears because hydrogen atoms …

From microporous to mesoporous molecular sieve materials and their use in catalysis

A Corma - Chemical reviews, 1997 - ACS Publications
It is possible to say that zeolites are the most widely used catalysts in industry. They are
crystalline microporous materials which have become extremely successful as catalysts for …

Lewis acids: from conventional homogeneous to green homogeneous and heterogeneous catalysis

A Corma, H Garcia - Chemical Reviews, 2003 - ACS Publications
Acid-catalyzed reactions are by far the most numerous and best-studied reaction type, 1-5 in
which organic functional groups undergo an array of different transformations with …

Activation of carbonyl-containing molecules with solid Lewis acids in aqueous media

Y Román-Leshkov, ME Davis - Acs Catalysis, 2011 - ACS Publications
Current interest in reacting carbonyl-containing molecules in aqueous media is primarily
due to the growing emphasis on conversion of biomass to fuels and chemicals. Recently …

Sulfated zirconia and its modified versions as promising catalysts for industrial processes

GD Yadav, JJ Nair - Microporous and mesoporous materials, 1999 - Elsevier
Zirconium oxide, or zirconia, when modified with anions such as sulfate ions forms a highly
acidic or superacidic catalyst depending on the treatment conditions. This catalyst is found to …

Structural and catalytic characterization of solid acids based on zirconia modified by tungsten oxide

DG Barton, SL Soled, GD Meitzner, GA Fuentes… - Journal of …, 1999 - Elsevier
Tungsten oxide species form strong acid sites on ZrO2supports and inhibit ZrO2crystallite
sintering and tetragonal to monoclinic structural transformations. W-LIX-ray absorption near …

Sulfated zirconia-based strong solid-acid catalysts: recent progress

X Song, A Sayari - Catalysis Reviews, 1996 - Taylor & Francis
This review article deals with recent progress in the preparation of sulfated zirconia (SZ)-
bassed, strong solid-acid catalysts, the characterization of their physicochemical properties …

A survey of the mechanism in catalytic isomerization of alkanes

Y Ono - Catalysis today, 2003 - Elsevier
The isomerization of alkanes into corresponding branched isomers is one of the important
processes in petroleum refining. Though the so-called bifunctional catalysts are used in …

Recent advances and future aspects in the selective isomerization of high n‐Alkanes

VM Akhmedov, SH Al‐Khowaiter - Catalysis Reviews, 2007 - Taylor & Francis
This article provides an overview of the advances that have been marked during the last
decades in the field of hydroconversion of high n‐alkanes (C7+) with particular stress on the …

Preparation of superacids by metal oxides for reactions of butanes and pentanes

K Arata - Applied Catalysis A: General, 1996 - Elsevier
Recent works on preparation of solid superacid catalysts which are active for reactions of
butanes and pentanes are reviewed. Sulfated metal oxides are obtained by adsorbing …