Mercury bis (phenyltellurolate) as a precursor for the synthesis of binary and ternary nanoclusters
The reaction of Hg (TePh) 2 with AgX (X= Cl, NO3) in the presence of PPh3 and PMePh2 in
dimethylformamide (DMF) affords the cluster [Hg6Ag4 (TePh) 16](1) at room temperature or …
dimethylformamide (DMF) affords the cluster [Hg6Ag4 (TePh) 16](1) at room temperature or …
Dealing with 1, 3-bis (4-nitrophenyl) triazene as intermediary ligand in the synthesis of polymeric (μ-Se) Hg-clusters: One-pot synthetic procedures and X-ray structural …
GA Casagrande, ES Lang, GM de Oliveira… - Inorganica Chimica …, 2007 - Elsevier
(PhSe) 2Hg reacts initially with HgBr2 and further with 1, 3-bis (4-nitrophenyl) triazene to
give [(PhSe) 7Hg4BrPy] n (Py= pyridine) the first polymeric assembling of (μ-Se) Hg clusters …
give [(PhSe) 7Hg4BrPy] n (Py= pyridine) the first polymeric assembling of (μ-Se) Hg clusters …
Cadmium bis (phenylselenolate) as a precursor for the synthesis of polymeric Cd (μ-Se) clusters: Crystal and molecular structures of [Cd4 (SePh) 7 (PPh3) X] n (X= Cl …
The reaction of Cd (SePh) 2 with CdX2 (X= Cl (1), Br (2)) in MeOH in the presence of PPh3
at 130° C under solvothermal conditions affords the products [Cd4 (SePh) 7 (PPh3) X] n, a …
at 130° C under solvothermal conditions affords the products [Cd4 (SePh) 7 (PPh3) X] n, a …
On the Use of Mercury Bis(Phenylselenolate) for the Synthesis of Polymeric Clusters: Synthesis and X-ray Structural Characterization of [Hg5Cl3(PhSe)7] n , [Hg7Cl3(PhSe)11] n and [Hg …
ES Lang, GM de Oliveira, B Tirloni, AB Lago… - Journal of Cluster …, 2009 - Springer
Abstract (PhSe) 2 Hg reacts in DMF with HgX 2 (X= Cl, Br) in the presence of bis (pyrimidin-2-
thio) methane/triphenylphosphine/4, 4′-bipyridine, to give the polymeric cages [Hg 5 Cl 3 …
thio) methane/triphenylphosphine/4, 4′-bipyridine, to give the polymeric cages [Hg 5 Cl 3 …
[HTML][HTML] Synthesis and characterization of [Cd8Cl2Se (SePh) 12 (PCy3) 2]· 2.5 CH3OH
In this article we present the synthesis of the compound [Cd8Cl2Se (SePh) 12 (PCy3) 2]· 2.5
CH3OH by the reaction of Cd (SePh) 2 with CdCl2 and PCy3 in methanol in a stainless steel …
CH3OH by the reaction of Cd (SePh) 2 with CdCl2 and PCy3 in methanol in a stainless steel …
New examples of the exploitation of intermediary ligands in the synthesis of polymeric (μ-Se) Hg-clusters
ES Lang, B Tirloni, GM de Oliveira, MA Villetti - Inorganica Chimica Acta, 2009 - Elsevier
(PhSe) 2Hg reacts initially with HgX2 (X= Cl, I) and further with triphenylphosphine/DMF to
give [(PhSe) 7Hg4ClPy] n (1) and [(PhSe) 7Hg4I (DMF)] n (2), polymeric assemblies of (μ …
give [(PhSe) 7Hg4ClPy] n (1) and [(PhSe) 7Hg4I (DMF)] n (2), polymeric assemblies of (μ …
Synthesis, structural characterization and growth features of some (Ph) Se–Cd cluster compounds (Ph= phenyl)
ES Lang, R Stieler, GM de Oliveira - Polyhedron, 2010 - Elsevier
Cd (SePh) 2, CdBr2· 4H2O/CdI2 and PCh3 (Ph= phenyl; PCh3= tricyclohexylphosphine)
react to give [(SePh) 2Cd2Br2 (PCh3) 2](1),[(SePh) 2Cd2I2 (PCh3) 2](2) and [(SePh) …
react to give [(SePh) 2Cd2Br2 (PCh3) 2](1),[(SePh) 2Cd2I2 (PCh3) 2](2) and [(SePh) …
On the synthesis and structure of HgSe clusters: Synthetic–structural considerations and optical features of new cluster compounds
R Stieler, F Bublitz, ES Lang, GM de Oliveira - Polyhedron, 2012 - Elsevier
MgCl2· 6H2O, MgBr2, MgI2, FeCl2, NiCl2 and dppp {1, 3-bis (diphenyl-phosphine) propane}
react with Hg (SePh) 2 in dimethylformamide (dmf) to give the new cluster compounds [M …
react with Hg (SePh) 2 in dimethylformamide (dmf) to give the new cluster compounds [M …
Improving the use of mercury bis (phenyltellurolate) as efficient start for the synthesis of ternary clusters and polymers
ES Lang, DF Back, GM de Oliveira - Polyhedron, 2008 - Elsevier
Hg (TePh) 2 reacts with AgCl/PMe2Ph and AgClO4/PPh3 to give the ternary clusters [(PhTe)
4Ag2Hg2 (Cl) 2] n (1) and [(PhTe) 16Ag4Hg6Py4]· H2O (2). While 1 assembles polymeric …
4Ag2Hg2 (Cl) 2] n (1) and [(PhTe) 16Ag4Hg6Py4]· H2O (2). While 1 assembles polymeric …
Synthesis and crystal structure of chalcogenide cluster compound
Three new cluster compounds were synthesized from Hg (EPh) 2 (E= Se, Te; Ph= phenyl) in
organic solvents. Two of these compounds,[Hg2Cl2 (SePh) 2 (PCy3) 2],(1), and [Hg2Br2 …
organic solvents. Two of these compounds,[Hg2Cl2 (SePh) 2 (PCy3) 2],(1), and [Hg2Br2 …