In this review article, we consider the use of molecular oxygen in reactions mediated by
polyoxometalates. Polyoxometalates are anionic metal oxide clusters of a variety of …

Abstract Polyoxometalates (POMs), anionic metal‐oxygen nanoclusters that possess various
composition‐dependent properties, are widely used to modify the existing properties of …

Polyoxometalate cluster anions (POMs) control formation and morphology, and serve as
protecting ligands, for structurally and compositionally diverse nanostructures. While …

The often astonishing material properties of crystalline biominerals are generally related to
the hierarchical assembly of specifically interacting organic and inorganic components. To …

Direct imaging of surface molecules and the interfaces between soft and hard materials on
functionalized nanoparticles is a great challenge using modern microscopy techniques. We …

A catalyst prepared by modifying the surface of Au nanoparticles (NPs) on Al2O3 with
[Nb6O19] 8− clusters had specific base and reduction abilities, and the reduction of p …

Cryogenic “trapping” was used to obtain the first TEM images of self-assembled monolayers
of inorganic anions on a gold nanoparticle. This unique structural information makes it …

Polyoxometalates (POMs) have been found to be good end-capping ligands for gold
nanoparticles (AuNPs). Herein, we introduce a new synthetic method to synthesize gold …

This review summarizes the progress in the research on polyoxometalate (POM)-decorated
gold (Au) and silver (Ag) core–shell structures (Au/Ag@ POMs), emphasizing their …

The metal oxide cluster α-AlW11O399–(1), readily imaged by cryogenic transmission
electron microscopy (cryo-TEM), is used as a diagnostic protecting anion to investigate the …