Green strategies for transition metal-catalyzed C–H activation in molecular syntheses

U Dhawa, N Kaplaneris, L Ackermann - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
Transition metal catalyzed C–H activation has surfaced as a powerful tool to improve the
efficacy of molecular synthesis. Last two decades have witnessed a considerable progress …

Heterogeneous catalytic approaches in C–H activation reactions

S Santoro, SI Kozhushkov, L Ackermann, L Vaccaro - Green Chemistry, 2016 - pubs.rsc.org
Despite the undisputed advances and progress in metal-catalyzed C–H functionalizations,
this atom-economical approach had thus far largely been developed with the aid of various …

Solvent free depolymerization of Kraft lignin to alkyl-phenolics using supported NiMo and CoMo catalysts

CR Kumar, N Anand, A Kloekhorst, C Cannilla… - Green …, 2015 - pubs.rsc.org
The catalytic hydrotreatment of Kraft lignin using sulfided NiMo and CoMo catalysts on
different acidic and basic supports (Al2O3, ZSM-5, activated carbon (AC) and MgO-La2O3) …

Acylation of (Hetero) Arenes through C H Activation with Aroyl Surrogates

XF Wu - Chemistry–A European Journal, 2015 - Wiley Online Library
In this Minireview, the major achievements in the acylation of arenes and heteroarenes by
C H activation with aroyl groups are summarized and discussed. As the products are …

Dual photoredox/palladium-catalyzed C–H acylation of 2-arylpyridines with oxime esters

BQ He, Y Gao, PZ Wang, H Wu, HB Zhou, XP Liu… - Synlett, 2021 - thieme-connect.com
An unprecedented dual photoredox/palladium-catalyzed iminyl-radical-mediated C–C bond
cleavage and directed ortho C–H acylation of 2-arylpyridines by using oxime esters is …

Efficient depolymerization of lignins to alkylphenols using phosphided NiMo catalysts

JO Velasco, I Van Der Linden, PJ Deuss… - Catalysis Science & …, 2021 - pubs.rsc.org
Greening up the chemical industry by using waste biomass streams as feed is a topic of high
relevance. Residual lignins from for example the pulp and paper industry and second …

Co (II)‐C12 alkyl carbon chain multi‐functional ionic liquid immobilized on nano‐SiO2 nano‐SiO2@CoCl3‐C12IL as an efficient cooperative catalyst for C–H …

YL Hu, YP Wu, M Lu - Applied Organometallic Chemistry, 2018 - Wiley Online Library
Nano‐silica supported ionic liquids composed of alkyl carbon chain and transition metal
chlorides anions have been prepared and successfully applied as a heterogeneous catalyst …

Synthesis of 6-aroyl phenanthridines by Fe-catalyzed oxidative radical cyclization of 2-isocyanobiphenyls with benzylic alcohols

Z Nie, Q Ding, Y Peng - Tetrahedron, 2016 - Elsevier
A practical method for the synthesis of 6-aroyl phenanthridine derivatives by Fe-catalyzed
oxidative radical cyclization of 2-isocyanobiphenyls with benzylic alcohols is described. In …

Supported Palladium Nanoparticles Catalyzed Ortho-Directed C–C Coupling Reaction via a Pd0/PdII/PdIV Catalytic Cycle

D Zhang, B Zhaorigetu, YS Bao - The Journal of Physical …, 2015 - ACS Publications
Catalyzed by supported palladium nanoparticles, an ortho-directed C–C coupling reaction
between 2-phenylpyridines and aldehydes has been developed for the selective synthesis …

Peroxide-mediated direct synthesis of amides from aroyl surrogates

G Hong, S Wu, X Zhu, D Mao, L Wang - Tetrahedron, 2016 - Elsevier
An efficient and metal-free method has been developed for the direct synthesis of amides
from readily available azobenzenes reacting with aroyl surrogates such as alcohols …