Conspectus Chain-walking offers extensive opportunities for innovating synthetic methods
that involve constructing chemical bonds at unconventional sites. This approach provides …

The precise construction of chiral molecules is a core research area in chemical science and
technology. Among the plethora of reported synthetic methods, asymmetric catalysis has …

This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …

Site-and enantio-selective alkyl–alkyl bond formation is privileged in the retrosynthetic
analysis due to the universality of sp3-hybridized carbon atoms in organic molecules …

Novel-substituted pyrrolidine derivatives are widely used in drugs and bioactive molecules.
The efficient synthesis of these valuable skeletons, especially enantiopure derivatives, is still …

C-Glycosides are important structures that are common to natural products and
pharmaceutical agents. Established methods for their synthesis involve the reaction of an …

A NiH‐catalyzed migratory hydroalkylation of alkenyl amines with predictable and
switchable regioselectivity is reported. By utilizing a ligand‐controlled, directing group …

Substituted six-membered cyclic hydrocarbons are common constituents of biologically
active compounds. Although methods for the synthesis of thermodynamically favored …

Organosilicon compounds have shown tremendous potential in drug discovery and their
synthesis stimulates wide interest. Multicomponent cross-coupling of alkenes with silicon …

Radical reactions play an important role in modern organic synthetic chemistry. The
generation of carbon radicals from the homolytic cleavage of carbon–metal bonds has been …