Recent advances in supramolecular fullerene chemistry
Fullerene chemistry has come a long way since 1990, when the first bulk production of C60
was reported. In the past decade, progress in supramolecular chemistry has opened some …
was reported. In the past decade, progress in supramolecular chemistry has opened some …
Switchable metallacycles and metallacages
Two-dimensional metallacycles and three-dimensional metallacages constructed by
coordination-driven self-assembly have attracted much attention because they exhibit …
coordination-driven self-assembly have attracted much attention because they exhibit …
Boryl Radical Activation of Benzylic C–OH Bond: Cross-Electrophile Coupling of Free Alcohols and CO2 via Photoredox Catalysis
WD Li, Y Wu, SJ Li, YQ Jiang, YL Li… - Journal of the …, 2022 - ACS Publications
A new strategy for the direct cleavage of the C (sp3)–OH bond has been developed via
activation of free alcohols with neutral diphenyl boryl radical generated from sodium …
activation of free alcohols with neutral diphenyl boryl radical generated from sodium …
Picking the lock of coordination cage catalysis
The design principles of metallo-organic assembly reactions have facilitated access to
hundreds of coordination cages of varying size and shape. Many of these assemblies …
hundreds of coordination cages of varying size and shape. Many of these assemblies …
Recent advances and perspectives on supramolecular radical cages
B Huang, L Mao, X Shi, HB Yang - Chemical Science, 2021 - pubs.rsc.org
Supramolecular radical chemistry has been emerging as a cutting-edge interdisciplinary
field of traditional supramolecular chemistry and radical chemistry in recent years. The …
field of traditional supramolecular chemistry and radical chemistry in recent years. The …
Host–guest-induced electron transfer triggers radical-cation catalysis
RL Spicer, AD Stergiou, TA Young… - Journal of the …, 2020 - ACS Publications
Modifying the reactivity of substrates by encapsulation is a fundamental principle of capsule
catalysis. Here we show an alternative strategy, wherein catalytic activation of otherwise …
catalysis. Here we show an alternative strategy, wherein catalytic activation of otherwise …
Confinement self-assembly of metal-organic cages within mesoporous carbon for one-pot sequential reactions
FF Zhu, LJ Chen, S Chen, GY Wu, WL Jiang, JC Shen… - Chem, 2020 - cell.com
Well-defined discrete metal-organic cages have been widely explored in the field of
supramolecular catalysis. However, these metal-organic cages have been rarely explored …
supramolecular catalysis. However, these metal-organic cages have been rarely explored …
A self‐assembled homochiral radical cage with paramagnetic behaviors
Condensation of an inherently C3‐symmetric polychlorotriphenylmethyl (PTM) radical
trisaldehyde with tris (2‐aminoethyl) amine (TREN) yields a [4+ 4] tetrahedral radical cage …
trisaldehyde with tris (2‐aminoethyl) amine (TREN) yields a [4+ 4] tetrahedral radical cage …
Inorganic–organic hybrid polyoxoniobates: polyoxoniobate metal complex cage and cage framework
ZK Zhu, YY Lin, H Yu, XX Li… - Angewandte Chemie …, 2019 - Wiley Online Library
The combination of polyoxoniobates (PONbs) with 3d metal ions, azoles, and organoamines
is a general synthetic procedure for making unprecedented PONb metal complex cage …
is a general synthetic procedure for making unprecedented PONb metal complex cage …
Formation of C–B, C–C, and C–X Bonds from Nonstabilized Aryl Radicals Generated from Diaryl Boryl Radicals
F Yue, H Ma, P Ding, H Song, Y Liu… - ACS Central Science, 2023 - ACS Publications
With the development of organoboron chemistry, boron-centered radicals have become
increasingly attractive. However, their synthetic applications remain limited in that they have …
increasingly attractive. However, their synthetic applications remain limited in that they have …