Fullerene chemistry has come a long way since 1990, when the first bulk production of C60
was reported. In the past decade, progress in supramolecular chemistry has opened some …

Two-dimensional metallacycles and three-dimensional metallacages constructed by
coordination-driven self-assembly have attracted much attention because they exhibit …

A new strategy for the direct cleavage of the C (sp3)–OH bond has been developed via
activation of free alcohols with neutral diphenyl boryl radical generated from sodium …

The design principles of metallo-organic assembly reactions have facilitated access to
hundreds of coordination cages of varying size and shape. Many of these assemblies …

Supramolecular radical chemistry has been emerging as a cutting-edge interdisciplinary
field of traditional supramolecular chemistry and radical chemistry in recent years. The …

Modifying the reactivity of substrates by encapsulation is a fundamental principle of capsule
catalysis. Here we show an alternative strategy, wherein catalytic activation of otherwise …

Well-defined discrete metal-organic cages have been widely explored in the field of
supramolecular catalysis. However, these metal-organic cages have been rarely explored …

Condensation of an inherently C3‐symmetric polychlorotriphenylmethyl (PTM) radical
trisaldehyde with tris (2‐aminoethyl) amine (TREN) yields a [4+ 4] tetrahedral radical cage …

The combination of polyoxoniobates (PONbs) with 3d metal ions, azoles, and organoamines
is a general synthetic procedure for making unprecedented PONb metal complex cage …

With the development of organoboron chemistry, boron-centered radicals have become
increasingly attractive. However, their synthetic applications remain limited in that they have …