Hypervalent (three-center, four-electron) bonding in organobismuth complexes has been
extensively studied due to its ability to affect molecular geometry, dynamic behavior, or to …

A monumental diversity of catalytic methods imparts the ability to select one of two
configurations of tetravalent stereocentres. Conversely, catalyst control over pentavalent …

O-Phosphination of α-dicarbonyls via sequential in situ formation of a Kukhtin–Ramirez
adduct and a P (NMe2) 3-catalyzed process has been exploited for the synthesis of α …

A light-driven method for the generation of aryl radicals from triarylbismuth (III) and (V)
reagents is described. Aryl radical generation is proposed to occur through the ligand …

A practical and regioselective direct N-alkylation of 2-pyridones is enabled by use of α-keto
esters in the P (NMe2) 3-mediated deoxygenation process. The reaction proceeds under …

An efficient synthesis of cyanohydrin esters via a P (NMe2) 3 mediated direct deoxygenation
process has been exploited, circumventing the release or transformation of the CN─ anion …

A novel copper-catalyzed cross-dehydrogenative-coupling (CDC) process of arylglycine
derivatives with N-heteroarenes for the straightforward synthesis of α-aryl-α-heteroaryl α …

Bismacycles featuring a sulfone-bridged scaffold have recently been developed as versatile
and convenient electrophilic arylating agents. Here, we report that the exocyclic aryl group …

Arylethylamines represent a privileged scaffold in pharmaceutical compounds and form the
backbone of many medical drugs, including those used for treating neurological diseases …

Simultaneous multiple displacements of organic molecules can lead to a large structural
reconstruction with increased complexity that would be difficult to access otherwise …