Photobiocatalytic strategies for organic synthesis

MA Emmanuel, SG Bender, C Bilodeau… - Chemical …, 2023 - ACS Publications
Biocatalysis has revolutionized chemical synthesis, providing sustainable methods for
preparing various organic molecules. In enzyme-mediated organic synthesis, most reactions …

Expanding the synthetic toolbox through metal–enzyme cascade reactions

S González-Granda, J Albarrán-Velo… - Chemical …, 2023 - ACS Publications
The combination of metal-, photo-, enzyme-, and/or organocatalysis provides multiple
synthetic solutions, especially when the creation of chiral centers is involved. Historically …

Fatty acids and their derivatives as renewable platform molecules for the chemical industry

U Biermann, UT Bornscheuer… - Angewandte Chemie …, 2021 - Wiley Online Library
Oils and fats of vegetable and animal origin remain an important renewable feedstock for the
chemical industry. Their industrial use has increased during the last 10 years from 31 to 51 …

Photo-biocatalysis: biotransformations in the presence of light

L Schmermund, V Jurkas, FF Özgen, GD Barone… - Acs …, 2019 - ACS Publications
Light has received increased attention for various chemical reactions but also in
combination with biocatalytic reactions. Because currently only a few enzymatic reactions …

Hydrogen peroxide driven biocatalysis

BO Burek, S Bormann, F Hollmann, JZ Bloh… - Green …, 2019 - pubs.rsc.org
In general, hydrogen peroxide is a stable and relatively mild oxidant and it can be regarded
as the ultimate “green” reagent because water and oxygen are the only by-products …

Light‐driven enzymatic decarboxylation of fatty acids

MME Huijbers, W Zhang, F Tonin… - Angewandte Chemie …, 2018 - Wiley Online Library
The photoenzymatic decarboxylation of fatty acids to alkanes is proposed as an alternative
approach for the synthesis of biodiesel. By using a recently discovered photodecarboxylase …

Chemoenzymatic cascades combining biocatalysis and transition metal catalysis for asymmetric synthesis

S González‐Granda, L Escot, I Lavandera… - Angewandte …, 2023 - Wiley Online Library
The combination of catalytic methods provides multiple advantages in organic synthesis,
allowing access to diverse organic molecules in a straightforward manner. Merging metal …

Photo‐biocatalytic cascades: combining chemical and enzymatic transformations fueled by light

FF Özgen, ME Runda, S Schmidt - ChemBioChem, 2021 - Wiley Online Library
In the field of green chemistry, light–an attractive natural agent–has received particular
attention for driving biocatalytic reactions. Moreover, the implementation of light to drive …

Light-driven biocatalytic oxidation

CH Yun, J Kim, F Hollmann, CB Park - Chemical Science, 2022 - pubs.rsc.org
Enzymes are the catalyst of choice for highly selective reactions, offering nature-inspired
approaches for sustainable chemical synthesis. Oxidative enzymes (eg, monooxygenases …

Lipase-catalyzed esterification in water enabled by nanomicelles. Applications to 1-pot multi-step sequences

V Singhania, M Cortes-Clerget… - Chemical …, 2022 - pubs.rsc.org
Esterification in an aqueous micellar medium is catalyzed by a commercially available
lipase in the absence of any co-factors. The presence of only 2 wt% designer surfactant …