Recent advances in organic reactions involving elemental sulfur

TB Nguyen - Advanced Synthesis & Catalysis, 2017 - Wiley Online Library
Elemental sulfur has been known since Antiquity and found widespread applications in the
preparation of black gunpowder, the synthesis of sulfuric acid as well as other sulfur …

Lanthanide amidinates and guanidinates in catalysis and materials science: a continuing success story

FT Edelmann - Chemical Society Reviews, 2012 - pubs.rsc.org
Today the rare-earth elements play a critical role in numerous high-tech applications. This is
why various areas of rare-earth chemistry are currently thriving. In organolanthanide …

Recent progress in the chemistry of metal amidinates and guanidinates: syntheses, catalysis and materials

FT Edelmann - Advances in organometallic chemistry, 2013 - Elsevier
This review provides a comprehensive overview of the most recent progress in chemistry
and applications of metal complexes containing heteroallylic ligands such as amidinates …

Dipolar Coupling as a Mechanism for Fine Control of Magnetic States in ErCOT-Alkyl Molecular Magnets

MG Bernbeck, AP Orlova, JD Hilgar… - Journal of the …, 2024 - ACS Publications
The design of molecular magnets has progressed greatly by taking advantage of the ability
to impart successive perturbations and control vibronic transitions in 4f n systems through …

Guanidinates as Alternative Ligands for Organometallic Complexes

F Carrillo-Hermosilla, R Fernández-Galán, A Ramos… - Molecules, 2022 - mdpi.com
For decades, ligands such as phosphanes or cyclopentadienyl ring derivatives have
dominated Coordination and Organometallic Chemistry. At the same time, alternative …

Lanthanide-and actinide-mediated terminal alkyne hydrothiolation for the catalytic synthesis of Markovnikov vinyl sulfides

CJ Weiss, SD Wobser, TJ Marks - Organometallics, 2010 - ACS Publications
The Markovnikov-selective lanthanide-and actinide-mediated, intermolecular hydrothiolation
of terminal alkynes by aliphatic, benzylic and aromatic thiols using Cp* 2LnCH (TMS) 2 …

Polysulfide coordination clusters of the lanthanides

YZ Ma, S Bestgen, MT Gamer… - Angewandte Chemie …, 2017 - Wiley Online Library
Abstract The reaction of [(DippForm) 2Ln (thf) 2] with an excess of elemental sulfur in toluene
resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm) …

Synthesis, structural characterization, and reactivity of mono (amidinate) rare-earth-metal bis (aminobenzyl) complexes

J Hong, L Zhang, K Wang, Z Chen, L Wu… - Organometallics, 2013 - ACS Publications
Three kinds of solvated lithium amidinates with different coordination models were obtained
via recrystallization of [PhC (NC6H4 i Pr2-2, 6) 2] Li (THF)(1a) in different solvents …

LMCT facilitated room temperature phosphorescence and energy transfer in substituted thiophenolates of Gd and Yb

VA Ilichev, AV Rozhkov, RV Rumyantcev… - Dalton …, 2017 - pubs.rsc.org
To obtain luminescent lanthanide complexes with a low energy LMCT state the 2-(2′-
mercaptophenyl) benzothiazolates, Ln (SSN) 3, and 2-(2′-mercaptophenyl) …

Insertion of isocyanate and isothiocyanate into the Ln–P σ-bond of organolanthanide phosphides

W Yi, J Zhang, L Hong, Z Chen, X Zhou - Organometallics, 2011 - ACS Publications
The synthesis, structure, and reactivity of organoyttrium phosphides toward phenyl
isocyanate (PhNCO) and phenyl isothiocyanate (PhNCS) are described. Reaction of …