Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

New strategies for the preparation of sinter‐resistant metal‐nanoparticle‐based catalysts

L Wang, L Wang, X Meng, FS Xiao - Advanced Materials, 2019 - Wiley Online Library
Supported metal nanoparticles are widely used as catalysts in the industrial production of
chemicals, but still suffer from deactivation because of metal leaching and sintering at high …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Tuning/exploiting strong metal-support interaction (SMSI) in heterogeneous catalysis

CJ Pan, MC Tsai, WN Su, J Rick, NG Akalework… - Journal of the Taiwan …, 2017 - Elsevier
Interactions between metals and supports are of fundamental interest in heterogeneous
catalysis. The electronic, geometric and bifunctional effects originating from Strong Metal …

[HTML][HTML] Activity enhancement of cobalt catalysts by tuning metal-support interactions

C Hernández Mejía, TW van Deelen… - Nature …, 2018 - nature.com
Interactions between metal nanoparticles and support materials can strongly influence the
performance of catalysts. In particular, reducible oxidic supports can form suboxides that can …

Catalysis chemistry of dimethyl ether synthesis

J Sun, G Yang, Y Yoneyama, N Tsubaki - ACS Catalysis, 2014 - ACS Publications
Dimethyl ether (DME) is receiving great attention as a clean alternative fuel, owing to the
increasing energy demand. Despite tremendous efforts, catalytic synthesis of DME via a …

Crystal-phase-depended strong metal-support interactions enhancing hydrodeoxygenation of m-cresol on Ni/TiO2 catalysts

B Cui, H Wang, J Han, Q Ge, X Zhu - Journal of Catalysis, 2022 - Elsevier
The relatively cheap and abundant Ni as a catalyst for hydrodeoxygenation (HDO) of
biomass lignin-derived phenolics at 350° C and atmospheric pressure suffers from …

Enhanced CO2 Methanation Activity of Ni/Anatase Catalyst by Tuning Strong Metal–Support Interactions

J Li, Y Lin, X Pan, D Miao, D Ding, Y Cui, J Dong… - ACS …, 2019 - ACS Publications
Strong metal–support interaction (SMSI) has been widely recognized for platinum-group
metals on reducible oxide supports. Herein we report that the catalytic activity of Ni catalyst …

A solar photothermocatalytic approach for the CO2 conversion: Investigation of different synergisms on CoO-CuO/brookite TiO2-CeO2 catalysts

R Fiorenza, M Bellardita, SA Balsamo… - Chemical Engineering …, 2022 - Elsevier
The photoactive features of the least common polymorph of TiO 2, ie brookite, were
combined with the thermocatalytic redox ones of cerium oxide, focusing on the effects of the …

Evidence of Highly Active Cobalt Oxide Catalyst for the Fischer–Tropsch Synthesis and CO2 Hydrogenation

G Melaet, WT Ralston, CS Li, S Alayoglu… - Journal of the …, 2014 - ACS Publications
Hydrogenations of CO or CO2 are important catalytic reactions as they are interesting
alternatives to produce fine chemical feedstock hence avoiding the use of fossil sources …